The vapour pressure of a solvent decreased by 10 mm of Hg when a non-volatile solute was added to the solvent. The mole fraction of the solute in solution is 0.2. What would be the mole fraction of the solvent if the decrease in vapour pressure is 20 mm of Hg:
1. 0.2
2. 0.4
3. 0.6
4 0.8
Camphor is often used in molecular mass determination because:
1. It has a very high cryoscopic constant
2. It is volatile
3. It is a solvent for organic substances
4. It is readily available
From the colligative properties of a solution, which one is the best method for the determination of molecular weight of proteins & polymers:
1. Osmotic pressure
2. Lowering of vapour pressure
3. Lowering of freezing point
4. Elevation in boiling point
A solution contains a non-volatile solute of molecular mass M2. The molecular mass of solute in terms of osmotic pressure is:
where:
m2 → Mass of solute
V → Volume of solution
\(\pi\) → Osmotic pressure
1.
2.
3.
4.
The ideal solution indicates:
1. | A – B attraction force is greater than A – A and B – B. |
2. | A – B attraction force is less than A – A and B – B. |
3. | Attraction force remains the same in A – A and B – B. |
4. | The volume of the solution is different from the sum of the volume of the solute and solvent. |
Beans get cooked earlier in a pressure cooker, because:
1. | The boiling point increases with increasing pressure |
2. | The boiling point decreases with increasing pressure |
3. | The extra pressure of the pressure cooker softens the beans |
4. | Internal energy is not lost while cooking in a pressure cooker |
If 22 g of benzene is dissolved in 122 g of carbon tetrachloride then the mass percentage of carbon tetrachloride (CCl4) is-
1. 82.72%
2. 83.72%
3. 84.72%
4. 85.72%
The partial pressure of ethane over a solution containing 6.56 × 10–2 g of ethane is 1 bar. If the solution contains 5.00 × 10–2 g of ethane, the partial pressure of the gas will be -
1. 0.66 bar
2. 0.96 bar
3. 0.76 bar
4. 0.19 bar
The positive deviations from Raoult’s law mean the vapour pressure is:
1. Higher than expected.
2. Lower than expected.
3. As expected.
4. None of the above
The vapour pressure of 1 molal solution of a non-volatile solute in water at 300 K would be -
(The vapour pressure of water at 300 K = 12.3 kPa)
1. | 21.08 kPa | 2. | 12.08 kPa |
3. | 33.08 kPa | 4. | 4.08 kPa |