A chelating agent has two or more than two donor atoms to bind to a single metal ion. Which of the following is not a chelating agent?
1. Thiosulphato
2. Oxalato
3. Glycinato
4. Ethane-1,2-diamine
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What kind of isomerism exists between (violet) and (greyish-green)?
1. Linkage isomerism
2. Solvate isomerism
3. Ionization isomerism
4. Coordination isomerism
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IUPAC name of is :
1. Platinum diaminechloronitrite
2. Chloronitrito-N-ammineplatinum (II)
3. Diamminechloridonitrito-N-platinum (II)
4. Diamminechloronitrito-N-platinate (II)
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Note: In the following questions match the items given in Columns I and II.
Match the complexions given in Column I with the hybridization and number of unpaired electrons given in Column II and assign the correct code :
|
Column I (Complex ion) |
|
Column II (Hybridisation, |
A. |
1. |
||
B. |
2. |
||
C. |
3. |
||
D. |
4. |
||
|
|
5. |
1. A (3) B (1) C (5) D (2)
2. A (4) B (3) C (2) D (1)
3. A (3) B (2) C (4) D (1)
4. A (4) B (1) C (2) D (3)
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Note: In the following questions match the items given in Columns I and II.
Match the complex species given in Column I with the possible isomerism given in Column II and assign the correct code :
|
Column I (Complex species) |
|
Column II (Isomerism) |
A. |
1. |
optical |
|
B. |
2. |
ionisation |
|
C. |
3. |
coordination |
|
D. |
4. |
geometrical |
|
|
|
5. |
linkage |
1. A (1) B (2) C (4) D (5)
2. A (4) B (3) C (2) D (1)
3. A (4) B (1) C (5) D (3)
4. A (4) B (1) C (2) D (3)
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Match the compounds given in Column I with the oxidation state of cobalt present in it (given in Column II) and assign the correct code.
Column I (Compound) |
Column II (Oxidation state of Co) |
||
A. |
1. |
+4 |
|
B. |
2. |
0 |
|
C. |
3. |
+1 |
|
D. |
4. |
+2 |
|
5. |
+3 |
1. A=(1), B=(2), C=(4), D=(5)
2. A=(4), B=(3), C=(2), D=(1)
3. A=(5), B=(1), C=(4), D=(2)
4. A=(4), B=(1), C=(2), D=(3)
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The hybridised state of Cu in [Cu(NH3 )4 ]2+ is
1. sp
2. sp2
3. sp3
4. dsp2
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How many hydrate isomers are possible for the molecular formula ?
1. One
2. Two
3. Three
4. Four
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If excess of AgNO3 solution is added to 100ml of 0.024M solution of dichlorobis(ethylene diamine) cobalt (III) Chloride, how many moles of AgCl will be precipitated?
1. 0.0012
2. 0.0016
3. 0.0024
4. 0.0048
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The shape of [NiCl4]2- and [PtCl4]2- respectively are
1. Square planar, Square planar
2. Tetrahedral, Tetrahedral
3. Tetrahedral, Square planar
4. Square planar, Tetrahedral
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