What kind of isomerism exists between CrH2O6Cl3 (violet) and Cr(H2O)5ClCl2.H2O (greyish-green)?

1.  Linkage isomerism

2.  Solvate isomerism

3.  Ionization isomerism

4.  Coordination isomerism

Subtopic:  Isomerism in Coordination Compounds |
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IUPAC name of PtNH32ClNO2 is :

1.  Platinum diaminechloronitrite

2.  Chloronitrito-N-ammineplatinum (II)

3.  Diamminechloridonitrito-N-platinum (II)

4.  Diamminechloronitrito-N-platinate (II)

Subtopic:  Introduction, Classification and Nomenclature |
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Note: In the following questions match the items given in Columns I and II.

Match the complexions given in Column I with the hybridization and number of unpaired electrons given in Column II and assign the correct code :

 

Column I (Complex ion)

 

Column II (Hybridisation,
number of unpaired electrons)

A.

CrH2O63+

1.

dsp2,1

B.

CoCN42-

2.

sp3d2,5

C.

NiNH362+

3.

d2sp3,3

D.

MnF64-

4.

sp3,4

 

 

5.

sp3d2,2

1.  A (3) B (1) C (5) D (2)

2.  A (4) B (3) C (2) D (1)

3.  A (3) B (2) C (4) D (1)

4.  A (4) B (1) C (2) D (3)

Subtopic:  Introduction, Classification and Nomenclature | VBT, CFT & their Limitations |
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Note: In the following questions match the items given in Columns I and II.

Match the complex species given in Column I with the possible isomerism given in Column II and assign the correct code :

 

Column I (Complex species)

 

Column II (Isomerism)

A.

CoNH34Cl2+

1.

optical

B.

cis-Coen2Cl2+

2.

ionisation

C.

CoNH35NO2Cl2

3.

coordination

D.

CoNH36CrCN6

4.

geometrical

 

 

5.

linkage

1.  A (1) B (2) C (4) D (5)

2.  A (4) B (3) C (2) D (1)

3.  A (4) B (1) C (5) D (3)

4.  A (4) B (1) C (2) D (3)

Subtopic:  Isomerism in Coordination Compounds |
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Match the compounds given in Column I with the oxidation state of cobalt present in it (given in Column II) and assign the correct code.

Column I (Compound)

Column II (Oxidation state of Co)

A.

CoNCSNH35SO3

1.

+4

B.

CoNH34Cl2SO4

2.

0

C.

Na4CoS2O33

3.

+1

D.

Co2CO8

4.

+2

5.

+3

1. A=(1), B=(2), C=(4), D=(5)

2. A=(4), B=(3), C=(2), D=(1)

3. A=(5), B=(1), C=(4), D=(2)

4. A=(4), B=(1), C=(2), D=(3)

Subtopic:  Introduction, Classification and Nomenclature |
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The hybridised state of Cu in [Cu(NH3 )4 ]2+ is

1. sp

2. sp2

3. sp3

4. dsp2

Subtopic:  VBT, CFT & their Limitations |
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How many hydrate isomers are possible for the molecular formula CoCl3·6H2O?

1. One

2. Two

3. Three

4. Four

Subtopic:  Isomerism in Coordination Compounds |
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If excess of AgNO3 solution is added to 100ml of 0.024M solution of dichlorobis(ethylene diamine) cobalt (III) Chloride, how many moles of AgCl will be precipitated?

1. 0.0012

2. 0.0016

3. 0.0024

4. 0.0048

Subtopic:  Introduction, Classification and Nomenclature |
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The shape of  [NiCl4]2-  and  [PtCl4]2- respectively are

1. Square planar, Square planar

2. Tetrahedral, Tetrahedral

3. Tetrahedral, Square planar

4. Square planar, Tetrahedral

Subtopic:  VBT, CFT & their Limitations |
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Which of the following compounds exhibit geometrical isomerism?

1. [Pt(NH3)2Cl2 ]

2. [Zn(NH3)2Cl2 ]

3. [Pt(NH3)3Cl]

4. All of the above

Subtopic:  Isomerism in Coordination Compounds |
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