${\mathrm{N}}_2$ and ${\mathrm{O}}_2$ are converted to monocations ${\mathrm{N}}_2^{+}$ and ${\mathrm{O}}_2^{+}$ respectively, which is wrong statements:

1. In ${\mathrm{N}}_2^{+}$, the $\mathrm{N}-\mathrm{N}$ bond weakens

2. In ${\mathrm{O}}_2^{+}$, the $\mathrm{O}-\mathrm{O}$ bond order increases

3. In ${\mathrm{O}}_2^{+}$, the paramagnetism decreases

4. ${\mathrm{N}}_2^{+}$ becomes diamagnetic

In which of the following transformations, the bond order has increased and the magnetic behavior has changed?

$1. {\mathrm{C}}_2^{+} \to {\mathrm{C}}_2$
$2. {\mathrm{NO}}^{+}\to \mathrm{NO}$
$3. {\mathrm{O}}_2 \to {\mathrm{O}}_2^{+}$
$4. {\mathrm{N}}_2 \to {\mathrm{N}}_2^{+}$

${\mathrm{BF}}_3$ and ${\mathrm{NF}}_3$ both are covalent compounds but ${\mathrm{NF}}_3$ is polar whereas ${\mathrm{BF}}_3$ is non-polar. This is because :

1. Nitrogen atom is smaller than boron atom

2. N-F bond is more polar than B-F bond

3. NF${}_3$ is pyramidal whereas BF${}_3$ is planar triangular

4. BF${}_3$ is electron deficient whereas NF${}_3$ is not

How many sp${}^2$ and sp-hybridised carbon atoms are present respectively in the following compound ?

1. 4, 2

2. 6, 0

3. 3, 3

4. 5, 1

Which molecule does not exist ?

$1. {\mathrm{OF}}_2$
$2. {\mathrm{OF}}_4$
$3. {\mathrm{SF}}_2$
$4. {\mathrm{SF}}_4$

The correct order of Cl-O bond order is

$1. {\mathrm{ClO}}_3^{-} < {\mathrm{ClO}}_4^{-} < {\mathrm{ClO}}_2^{-} < {\mathrm{ClO}}^{-}$
$2. {\mathrm{ClO}}^{-} < {\mathrm{ClO}}_4^{-} < {\mathrm{ClO}}_3^{-} < {\mathrm{ClO}}_2^{-}$
$3. {\mathrm{ClO}}^{-} < {\mathrm{ClO}}_2^{-} < {\mathrm{ClO}}_3^{-}< {\mathrm{ClO}}_4^{-}$
$4. {\mathrm{ClO}}_4^{-} < {\mathrm{ClO}}_3^{-} < {\mathrm{ClO}}_2^{-} < {\mathrm{ClO}}^{-}$

0.01 mole of ${\mathrm{H}}_3{\mathrm{PO}}_{\mathrm{x}}$ is completely neutralized by 0.56 gram of KOH hence :

1. x = 3 and given acid is dibasic

2. x = 2 and given acid is monobasic

3. x = 3 and given acid is monobasic

4. x = 4 and given acid forms three series of salt

The shape of ${\mathrm{XeF}}_3^{+}$ is :

1. Trigonal planar

2. Pyramidal

3. Bent T-shape

4. See-saw

Which is the following pairs of species have identical shapes ?

$1. {\mathrm{NO}}_2^{+} \mathrm{and} {\mathrm{NO}}_2^{-}$
$2. {\mathrm{PCI}}_5 \mathrm{and} {\mathrm{BrF}}_5$
$3. {\mathrm{XeF}}_4 \mathrm{and} {\mathrm{ICI}}_4^{-}$
$4. {\mathrm{TeCl}}_4 \mathrm{and} {\mathrm{XeO}}_4$

Which of the following leads to bonding orbital?

1.
2.
3.
4.