Alkyl halide (RX) on treatment with KCN followed by reduction leads to the formation of:

1. RNH2

2. RCH2NH2

3. RH + NH3

4. RCH3 + N2

Subtopic:  Cyanides & Isocyanides |
 89%
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The end product in the following sequence of reactions is -

C2H5NH2HNO2A PCl5BNH3C?

1. Ethyl cyanide

2. Ethylamine

3. Methylamine

4. Acetamide

Subtopic:  Amines - Preparation & Properties |
 81%
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The product[A] formed in the reaction; 2C5H5-CNEt2ONa [A] is:C

1. 

2. 

3. 

4. 

Subtopic:  Amines - Preparation & Properties |
 53%
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Identfy X in the sequence,

X HNO2C3H8O H2SO4K2Cr2O7C3H6O2 :

1. CH3-NH-CH2-CH3

2. CH3-CH2-CH2-NH2

3. (CH3)3N

4. none of the above

Subtopic:  Identification of Primary, Secondary & Tertiary Amines |
 83%
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CH3CH2NH2 contains a basic NH2 group, but CH3CONH2 does not, because;

1. acetamide is amphoteric in character

2. in CH3CH2NH2 the electron pair on N-atom is delocalized by resonance

3. in CH3CH2NH2 there is no resonance, while in acetamide the lone pair of electron on N-atom is delocalized and therefore less available for protonation

4. none of the above

Subtopic:  Diazonium Salts: Preparation, Properties & Uses |
 80%
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Dehydration of an amide gives:

1. Cyanide

2. Amine

3. Isocyanide

4. Fatty acid

Subtopic:  Cyanides & Isocyanides |
 61%
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Tertiary nitro compounds cannot show tautomerism because:

1. they are very stable

2. isomerises to give sec. nitro compounds

3. do not have labile H-atom

4. they are highly eactive

Subtopic:  Identification of Primary, Secondary & Tertiary Amines |
 81%
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A secondary amine is:

1. a compound with two -NH2 groups

2. a compound with 2 carbon atoms and a -NH2 group

3. a compound with a -NH2 group on the carbon atom in number 2 position

4. a compound in which 2 of the hydrogens of NH3 have been replaced by alkyl or aryl groups

Subtopic:  Identification of Primary, Secondary & Tertiary Amines |
 75%
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Compound that will undergo Hoffmann reaction is-

1. RCONHCH3

2. RCOONH4

3. RCONH2

4. RCONHOH

Subtopic:  Amines - Preparation & Properties |
 89%
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The reagent required to convert acetamide into methyl amine is :

1. NaOH/ Br2

2. Sodalime

3. Hot conc. H2SO4

4. PCl5

Subtopic:  Amines - Preparation & Properties | Mechanism |
 86%
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AIPMT - 2010
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