$\left(\mathrm{X}\right)+{\mathrm{K}}_2{\mathrm{CO}}_3+\mathrm{Air}\stackrel{\mathrm{heat}}{\to }\left(\mathrm{Y}\right)$
$\left(\mathrm{Y}\right)+{\mathrm{Cl}}_2\stackrel{}{\to }\left(\mathrm{Z}\right)\mathrm{Pink}$

Which of the following is correct?

(a) X= black, ${\mathrm{MnO}}_2$,Y=Blue, ${\mathrm{K}}_2{\mathrm{CrO}}_4$, Z = ${\mathrm{KMnO}}_4$

(b) X= green, ${\mathrm{Cr}}_2{\mathrm{O}}_3$, Y=Yellow ,${\mathrm{K}}_2{\mathrm{CrO}}_4$, Z = ${\mathrm{K}}_2{\mathrm{Cr}}_2{\mathrm{O}}_7$

(c) X= black, ${\mathrm{MnO}}_2$, Y = green, ${\mathrm{K}}_2{\mathrm{MnO}}_4$, z = ${\mathrm{KMnO}}_4$

(d) x = black, ${\mathrm{Bi}}_2{\mathrm{O}}_3$, Y = Colourless, ${\mathrm{KBiO}}_2$, z = ${\mathrm{KBiO}}_3$

Consider the following transformation:

$2{\mathrm{CuX}}_2\stackrel{\mathrm{Room} \mathrm{temperature}}{\to }2\mathrm{CuX}+{\mathrm{X}}_2$

Then ${\mathrm{X}}^{-}$ can be:

(1) ${\mathrm{F}}^{-}, {\mathrm{Br}}^{-}$                         

(2) ${\mathrm{Cl}}^{-},{\mathrm{Br}}^{-}$

(3) ${\mathrm{CN}}^{-},{\mathrm{I}}^{-}$                         

(4) ${\mathrm{Cl}}^{-},{\mathrm{F}}^{-}$

Acidified permanganate solution does not oxidize:

(1) ${\mathrm{C}}_2{\mathrm{O}}_4^{2-}\left(\mathrm{aq}\right)$                   

(2) ${\mathrm{NO}}_2^{-}\left(\mathrm{aq}\right)$

(3) ${\mathrm{S}}^{2-}\left(\mathrm{aq}\right)$                         

(4) ${\mathrm{F}}^{-}\left(\mathrm{aq}\right)$

Which of the following statements is incorrect?

Which of the following is true for the species $3{\mathrm{d}}^4$ configuration ?

(1) ${\mathrm{Cr}}^{2+}$ is reducing in nature                               

(2) ${\mathrm{Mn}}^{3+}$ is oxidising in nature.

(3) Both (A) and (B)                                             

(4) None of these

In which compound does vanadium have an oxidation number of +4?

(A) ${\mathrm{NH}}_4{\mathrm{VO}}_2$                                 

(B) ${\mathrm{K}}_4\left[\mathrm{V}{\left(\mathrm{CN}\right)}_6\right]$

(C) ${\mathrm{VSO}}_4$                                     

(D) ${\mathrm{VOSO}}_4$

Among the following, the species that is both paramagnetic and coloured is :

(A) ${\left[{\mathrm{MnO}}_4\right]}^{2-}$                                     

(B) ${\left[{\mathrm{TiCl}}_6\right]}^{2-}$ 

(C) ${\left[{\mathrm{VO}}_4\right]}^{3-}$                                       

(D) ${\mathrm{CrO}}_2{\mathrm{Cl}}_2$

Arrange the following species in the increasing order of their magnetic properties.

${\mathrm{VCl}}_3$    ${\mathrm{VOSO}}_4$    ${\mathrm{Na}}_3{\mathrm{VO}}_4$       $\left[\mathrm{V}{\left({\mathrm{H}}_2\mathrm{O}\right)}_6\right]{\mathrm{SO}}_4.{\mathrm{H}}_2\mathrm{O}$

  I              II                  III                      IV

(1) III<II<I<IV                                         

(2) III<IV<II<I

(3) II<III<I<IV                                         

(4) IV<I<II<III

Which of the following increasing order of oxidising power is correct for the following species?

           ${{\mathrm{VO}}_2}^{+}, {{\mathrm{MnO}}_4}^{-}, {\mathrm{Cr}}_2{{\mathrm{O}}_7}^{2-}$

(A) ${{\mathrm{VO}}_2}^{+}<{\mathrm{Cr}}_2{{\mathrm{O}}_7}^{2-}<{{\mathrm{MnO}}_4}^{-}$                           

(B) ${{\mathrm{VO}}_2}^{+}<{{\mathrm{MnO}}_4}^{-}<{\mathrm{Cr}}_2{{\mathrm{O}}_7}^{2-}$

(C) ${\mathrm{Cr}}_2{{\mathrm{O}}_7}^{2-}<{{\mathrm{VO}}_2}^{+}<{{\mathrm{MnO}}_4}^{-},$                           

(D) ${\mathrm{Cr}}_2{{\mathrm{O}}_7}^{2-}<{{\mathrm{MnO}}_4}^{-}<{{\mathrm{VO}}_2}^{+}$

In which of the following oxoanions the oxidation state of the central atom is not the same as that of its group number in the periodic table?

(A) ${{\mathrm{MnO}}_4^{}}^{-}$                               

(B) ${\mathrm{Cr}}_2{\mathrm{O}}_7^{2-}$

(C) ${\mathrm{VO}}_4^{3-}$                                 

(D) ${\mathrm{FeO}}_4^{2-}$