Osmotic pressure is 0.0821 atm at a temperature of 300 K. Find concentration in mole/litre [Roorkee 1990]
(1) 0.033
(2) 0.066
(3) 0.33 × 10–2
(4) 3
The osmotic pressure of 5 % (mass-volume) solution of cane sugar at 150 °C (mol. mass of sugar = 342 g/mole) is:
1. | 4 atm | 2. | 5.07 atm |
3. | 3.55 atm | 4. | 2.45 atm |
A solution containing 3.3 g of a substance in 125 g of benzene (b.p. 80°C) boils at 80.66°C. If Kb for one litre of benzene is 3.28°C, the molecular weight of the substance shall be
1. 127.20
2. 131.20
3. 137.12
4. 142.72
The molal b.p. constant for water is . When 0.1 mole of sugar is dissolved in 200 g of water, the solution boils under a pressure of 1 atm at
(1) 100.513°C
(2) 100.0513°C
(3) 100.256°C
(4) 101.025°C
An aqueous solution containing 1 g of urea boils at 100.25 °C. The aqueous solution containing 3 g of glucose in the same volume will boil at:
1. 100.75 °C
2. 100.5 °C
3. 100 °C
4. 100.25 °C
Solution of sucrose (Mol. Mass = 342) is prepared by dissolving 34.2 gm of it in 1000 gm of water. Freezing point of the solution is (Kf for water is 1.86 K kg mol–1) [AIEEE 2003]
(1) 272.814 K
(2) 278.1 K
(3) 273.15 K
(4) 270 K
An aqueous solution of a weak monobasic acid containing 0.1 g in 21.7 g of water freezes at 272.817K. If the value of Kf for water is 1.86 K kg mol–1, the molecular mass of the acid is [AMU 2002]
(1) 46.0
(2) 48.6
(3) 48.8
(4) 46.8
What is the molality of the solution of a certain solute in a solvent if there is a freezing point depression of 0.184° and if the freezing point constant is 18.4 K kg
1. 0.01
2. 1.00
3. 0.001
4. 100
A solution containing 6.8 g of a non-ionic solute in 100 g of water was found to freeze at −0.93 oC. The freezing point depression constant of water is 1.86. The molecular weight of the solute is-
1. | 13.6 m | 2. | 34 m |
3. | 68 m | 4. | 136 m |
The molar freezing point constant for water is 1.86°C/mole. If 342 g of cane sugar is dissolved in 1000 g of water, the solution will freeze at
1. –1.86°C
2. 1.86°C
3. –3.92°C
4. 2.42°C