Stanley Miller had put the Oparin-Haldane theory to test in 1953 by creating in the laboratory, the probable conditions on the primitive earth. In the experiment simple amino acids were synthesized from which of the following mixtures, as observed after eighteen days?
1. \(H_2, O_2, N_2~ \text {and}~ H_2O\)
2. \(CH_4, CN , H_2~ \text {and}~ O_2\)
3. \(H_2, NH_3, CH_4\) and water vapour
4. \(NH_3, CH_4 ~\text {and} ~O_2\)