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Q. No.The correct order of bond angles in the following compounds/ species is:
1.
\(\mathrm{H}_2 \mathrm{O}<\mathrm{NH}_3<\mathrm{NH}_4^{+}<\mathrm{CO}_2 \)
2.
\(\mathrm{H}_2 \mathrm{O}<\mathrm{NH}_4^{+}<\mathrm{NH}_3<\mathrm{CO}_2 \)
3.
\(\mathrm{H}_2 \mathrm{O}<\mathrm{NH}_4^{+}=\mathrm{NH}_3<\mathrm{CO}_2 \)
4.
\(\mathrm{CO}_2<\mathrm{NH}_3<\mathrm{H}_2 \mathrm{O}<\mathrm{NH}_4^{+} \)
Subtopic: V.S.E.P.R & V.B.T |
67%
Level 2: 60%+
NEET - 2022
Hints
Match molecules in List-I with the Corresponding shape in List-II:
Choose the correct answer from the options given below:
| List-I (Molecules) |
List-II (Shape) |
||
| (a) | NH3 | (i) | Square pyramidal |
| (b) | ClF3 | (ii) | Trigonal bipyramidal |
| (c) | PCl5 | (iii) | Trigonal pyramidal |
| (d) | BrF5 | (iv) | T-shape |
| (a) | (b) | (c) | (d) | |
| 1. | (ii) | (iii) | (iv) | (i) |
| 2. | (iii) | (iv) | (ii) | (i) |
| 3. | (iv) | (iii) | (i) | (ii) |
| 4. | (iii) | (iv) | (i) | (ii) |
Subtopic: V.S.E.P.R & V.B.T |
82%
Level 1: 80%+
NEET - 2022
Hints
Which one of the following is the correct order of decreasing bond enthalpies for the given species?
1. \(\mathrm {O^{2-}_2>O^-_2>O_2>N_2 }\)
2. \(\mathrm {N_2>O_2>O^{2-}_2>O^-_2 }\)
3. \(\mathrm {N_2>O_2>O^-_2>O^{2-}_2 }\)
4. \(\mathrm {O_2>N_2>O^-_2>O^{2-}_2 }\)
Subtopic: M.O.T |
75%
Level 2: 60%+
NEET - 2022
Hints
Which one of the following statements is true about the structure of \(\mathrm{CO^{2-}_3}\) ion?
| 1. | It can be explained by considering sp3 hybridization. |
| 2. | Out of the three C–O bonds, two are longer and one is shorter. |
| 3. | It has three sigma and three \(\pi\)-bonds. |
| 4. | All three C–O bonds are equal in length with a bond order in between 1 and 2. |
Subtopic: Resonance & Nature of Compounds |
55%
Level 3: 35%-60%
NEET - 2022
Hints
Which of the following species will exhibit the maximum lone pair–lone pair electron repulsions?
1. \(\mathrm{XeF_2}\)2. \(\mathrm{ClF_3}\)
3. \(\mathrm{IF_5}\)
4. \(\mathrm{SF_4}\)
Subtopic: V.S.E.P.R & V.B.T |
77%
Level 2: 60%+
NEET - 2022
Hints
Identify the incorrect statement among the following options:
| 1. | \(O^+_2\) ion is diamagnetic. |
| 2. | The bond orders of \(O_2^{+},O_2,O^-_2\) and \(O_2^{2-}\) are 2.5, 2, 1.5, and 1, respectively. |
| 3. | \(C_2\) molecule has four electrons in its two degenerate \(\pi \) molecular orbitals. |
| 4. | \(H^+_2 \) ion has one electron. |
Subtopic: M.O.T |
79%
Level 2: 60%+
NEET - 2022
Hints
The correct order of energies of molecular orbitals of N2 molecule is:
| 1. | \( \sigma \text { 1s }<\sigma^* \text { 1s }<\sigma 2 s<\) \(\sigma^* 2 s<\left(\pi 2 p_x=\pi 2 p_y\right)<\) \(\left(\pi^* 2 p_x=\pi^* 2 p_y\right)<\sigma 2 p_z<\sigma^* 2 p_z\) |
| 2. | \( \sigma \text { 1s }<\sigma^* \text { 1s }<\sigma 2 s<\sigma^* 2 s<\) \(\left(\pi 2 p_x=\pi 2 p_y\right)< \) \(\sigma 2 p_z<\left(\pi^* 2 p_x=\pi^* 2 p_y\right)<\sigma^* 2 p_z \) |
| 3. | \( \sigma \text { 1s }<\sigma^* \text { 1s }<\sigma 2 s<\sigma^* 2 s<\sigma 2 p_z<\) \( \left(\pi 2 p_x=\pi 2 p_y\right)<\) \(\left(\pi^* 2 p_x=\pi^* 2 p_y\right)<\sigma^* 2 p_z \) |
| 4. | \( \sigma \text { 1s }<\sigma^* \text { 1s }\) \(<\sigma 2 s<\sigma^* 2 s<\sigma 2 p_z< \) \( \sigma^* 2 p_z<\left(\pi 2 p_x=\pi 2 p_y\right)<\) \(\left(\pi^* 2 p_x=\pi^* 2 p_y\right) \) |
Subtopic: M.O.T |
73%
Level 2: 60%+
NEET - 2023
Hints
Consider the following five chemical species:
NH₃, AlCl₃, BeCl₂, CCl₄ and PCl₅
How many of these species violate the octet rule by having either fewer or more than
eight electrons in the valence shell of their central atom?
| 1. | One | 2. | Three |
| 3. | Two | 4. | Four |
Subtopic: Octate, Isoelectronic Species, Lewis Structure & Formal Charge |
62%
Level 2: 60%+
NEET - 2023
Hints
The correct order of dipole moments for molecules \(NH_3, H_2S , CH_4 \) and \(HF\) is :
| 1. | \(CH_4>H_2S>NH_3>HF \) |
| 2. | \(H_2S>NH_3>HF>CH_4 \) |
| 3. | \(NH_3>HF>CH_4>H_2~S \) |
| 4. | \(HF>NH_3>H_2S>CH_4\) |
Subtopic: Polarity |
67%
Level 2: 60%+
NEET - 2023
Hints
Which one of the following statements is incorrect related to Molecular Orbital Theory?
| 1. | The \(\pi^*\) antibonding molecular orbital has a node between the nuclei. |
| 2. | In the formation of a bonding molecular orbital, the two electron waves of the bonding atoms reinforce each other. |
| 3. | Molecular orbitals obtained from \(2P_x\) and \(2P_y\) orbitals are symmetrical around the bond axis. |
| 4. | A \(\pi-\)bonding molecular orbital has larger electron density above and below the internuclear axis. |
Subtopic: M.O.T |
52%
Level 3: 35%-60%
NEET - 2023
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