Nalorphene (C19H21NO3), similar to morphine, is used to combat withdrawal symptoms in narcotic users. The dose of nalorphene generally given is 1.5 mg.
Calculate the mass of 1.5 × 10−3m aqueous solution required for the above dose.
1. 13.22 g
2. 3.22 g
3. 11.22 g
4. 9.22 g
The amount of benzoic acid (C6H5COOH) required for preparing 250 mL of 0.15 M solution in methanol is:
1. | 4.57 g | 2. | 3.57 g |
3. | 1.57 g | 4. | 12.57 g |
The depression in the freezing point of water was observed for the same amount of acetic acid, trichloroacetic acid, and trifluoroacetic in the order of-
1. acetic acid < trichloroacetic acid < trifluoroacetic acid
2. acetic acid > trichloroacetic acid > trifluoroacetic acid
3. acetic acid < trichloroacetic acid > trifluoroacetic acid
4. acetic acid > trichloroacetic acid < trifluoroacetic acid
The depression in the freezing point of water when 10 g of CH3CH2CHClCOOH is added to 250 g of water will be:
(Ka = 1.4 × 10–3, Kf = 1.86 K kg mol–1)
1. 0.32 K
2. 2.87 K
3. 0.65 K
4. 5.03 K
19.5 g of CH2FCOOH is dissolved in 500 g of water. The van’t Hoff factor and dissociation constant of fluoroacetic acid will be respectively: ( = 1.00 K )
1. | 20.75 , 4.77 × 10–3 | 2. | 1.075 , 4.77 × 10–2 |
3. | 2.073 , 3.07 × 10–4 | 4. | 1.075 , 3.07 × 10–3 |
100 g of liquid A (molar mass 140 g mol–1) was dissolved in 1000 g of liquid B (molar mass 180 g mol–1). The vapour pressure of pure liquid B was found to be 500 torr. If the total vapour pressure of the solution is 475 torr, the vapour pressure of pure liquid A will be:
1. | 326 torr | 2. | 226 torr |
3. | 360.7 torr | 4. | 280.7 torr |
The major component of air is nitrogen with approximately 79% by volume at 298 K. The water is in equilibrium with air at a pressure of 10 atm. At 298 K. if the Henry’s law constant for nitrogen at 298 K is 6.51 × 107 mm respectively, then the composition of nitrogen in air will be :
1. 12.4 × 10−5
2. 9.22 × 10−5
3. 3.54 × 10−5
4. 4.96 × 10−5
The amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27 °C is:
1. | 1.02 g | 2. | 4.35 g |
3. | 2.87 g | 4. | 3.42 g |
If 22 g of benzene is dissolved in 122 g of CCl4, the mass percentage of CCl4 and benzene respectively are-
1.
2.
3.
4. 91.28 %, 8.72 %
The type of inter molecular interactions present in
(a) | Methanol and Acetone | (i) | Van der Waal’s forces of attraction |
(b) | Acetonitrile and Acetone | (ii) | ion-dipole interaction |
(iii) | dipole-dipole interaction |
(a) | (b) | |
1. | (iii) | (ii) |
2. | (ii) | (ii) |
3. | (iii) | (iii) |
4. | (iii) | (i) |