In which of the following gaseous reaction, Kp and Kc have the same values?

1. 2HIH2+I2

2. N2+3H22NH3

3. 2SO2+O22SO3

4. PCI5PCII3+Cl2

Subtopic:  Kp, Kc & Factors Affecting them |
 91%
Level 1: 80%+
Hints

Find the gaseous equilibrium for which Kp < Kc.

1. PCl₅(g) ⇌ PCl₃(g) + Cl₂(g)
2. N₂(g) + O₂(g) ⇌ 2NO(g)
3. 2HI(g) ⇌ H₂(g) + I₂(g)
4. N₂(g) + 3H₂(g) ⇌ 2NH₃(g)

Subtopic:  Kp, Kc & Factors Affecting them |
 84%
Level 1: 80%+
Hints

Find the value of Kp for the reaction:

N₂(g) + 3H₂(g) ⇌ 2NH₃(g)

Given: Kc = 0.5 at 400 K and R = 0.0821 L atm mol⁻¹ K⁻¹.

1. 25.6 × 10⁻²
2. 4.6 × 10⁻⁴
3. 46.6 × 10⁻⁴
4. 16.6 × 10⁻⁸
Subtopic:  Kp, Kc & Factors Affecting them |
 72%
Level 2: 60%+
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Find the value of Kc for the reaction:

2SO₂(g) + O₂(g) ⇌ 2SO₃(g)

at 700 K, if

Kₚ = 1.3 × 10⁻³ atm⁻¹

1. 1.4 × 10⁻²
2. 7.4 × 10⁻²
3. 5.2 × 10⁻²
4. 3.1 × 10⁻²
Subtopic:  Kp, Kc & Factors Affecting them |
 80%
Level 1: 80%+
Hints

Find the ratio Kp/Kc for the reaction:

SO₂(g) + ½O₂(g) ⇌ SO₃(g)

1. (RT)1/2 

2. (RT)-1/2 

3. (RT)

4. 1

Subtopic:  Kp, Kc & Factors Affecting them |
 87%
Level 1: 80%+
Hints

Find the equilibrium constant Kc for the reaction:

½N₂(g) + ½O₂(g) + ½Br₂(g) ⇌ NOBr(g)

Given:

2NO(g) ⇌ N₂(g) + O₂(g)  Kc₁ = 2.5 × 10³⁰

NO(g) + ½Br₂(g) ⇌ NOBr(g)  Kc₂ = 1.6
 

1. 1.01 × 10⁻¹⁵
2. 2.02 × 10⁻¹⁵
3. 1.01 × 10³⁰
4. 2.02 × 10¹⁵
Subtopic:  Kp, Kc & Factors Affecting them |
 63%
Level 2: 60%+
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If Kp of the reaction A(g)+2B(g)3C(g)+D(g) is 0.05 at 1000 K, then the value of Kc of the reaction

1. 20000 R

2. 0.02 R

3. 5×10-5R

4. 5×10-5R

Subtopic:  Kp, Kc & Factors Affecting them |
 86%
Level 1: 80%+
Hints

What will be the change in the concentration of Cl₂ when the equilibrium concentration of PCl₃ is doubled in the reaction:

PCl₅(s) ⇌ PCl₃(g) + Cl₂(g)?

1. Cl₂ becomes half of its initial concentration

2. Cl₂ becomes one-fourth of its initial concentration

3. Cl₂ becomes four times its initial concentration

4. Cl₂ becomes twice its initial concentration

Subtopic:  Introduction To Equilibrium |
 75%
Level 2: 60%+
Hints

In the reaction, the equilibrium concentrations of PCl5 and PCl3 are 0.4 and 0.2 mole/liter respectively. If the value of Kc is 0.5, what is the concentration of Cl2 in mole/liter?

1. 2.0

2. 1.5

3. 1.0

4. 0.5

Subtopic:  Ionisation Constant of Acid, Base & Salt |
 85%
Level 1: 80%+
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4 moles each of SO2 and O2 gases are allowed to react to form SO3 in a closed vessel. At equilibrium, 25% of O2 is used up. The total number of moles of all the gases at equilibrium is

1. 6.5

2. 7.0

3. 8.0

4. 2.0

Subtopic:  Introduction To Equilibrium |
 70%
Level 2: 60%+
Hints