In the reaction sequence,

[X] will be:

1.		2.	$C{H}_{3}COOH$
3.	$C_6{H}_5-N{H}_2$	4.	$C{H}_3-CO-NH-C_6{H}_5$

Consider the following statements for carbonyl compounds:

(i) They give nucleophilic addition reaction.

(ii) Aldehyde is more reactive than ketone for nucleophilic addition reaction.

(iii) $\beta -$hydrogen of carbonyl compound is more acidic than $\alpha -$hydrogen.

(iv) They give addition reaction followed by elimination reaction with $N{H}_2-NH-C_6{H}_4-C{H}_3$.

Of these statements:

(1) (i) and (ii) are correct

(2) (i), (ii) and (iv) are correct

(3) (i), (ii) and (iii) are correct

(4) (i), (ii), (iii) and (iv) are correct

Consider the following statements for a carbonyl compound:

(i) It gives addition reaction

(ii) It gives condensation reaction

(iii) It gives elimination reaction

(iv) It gives oxidation reaction

Of these statements:

(1) (i), (ii), (iii) and (iv) are correct

(2) (i) and (ii) are correct

(3) (i), (ii) and (iii) are correct

(4) (i), (ii) and (iv) are correct

Which compound will give E1cb reaction?

(1) $C{F}_3-CHC{l}_2$

(2) $C_6{H}_5-C{H}_2-C{H}_2-F$

(3) $N{O}_2$
$l$
$C{H}_3-CH-CH{C}_6{H}_5$
$l$
$OCOC{H}_3$

(4) All of these

Reaction intermediate of E1 reaction is:

(1) Carbocation

(2) carbanion

(3) Carbene

(4) free radical

Reaction intermediate of E1cb reaction is:

1. Carbocation

2. Carbanion

3. benzyne

4. free radical

In the given reaction:

${\mathrm{CH}}_3-{\mathrm{CH}}_2-\underset{{\mathrm{CH}}_3}{\underset{|}{\mathrm{CH}}}-{\mathrm{CH}}_2-\mathrm{Br}\stackrel{\mathrm{alc}.\mathrm{KOH}/∆}{\to }\left[\mathrm{X}\right]$

[X] will be:

(1) $C{H}_3-C{H}_2-C=C{H}_2$
$I$
$C{H}_3$

(2) $C{H}_3-CH=C-C{H}_3$
$l$
$C{H}_3$

(3) $C{H}_2=CH-CH-C{H}_3$
$l$
$C{H}_3$

(4) $C{H}_3-CH=CH-C{H}_2-C{H}_3$

Which one of the following is correctly matched?

1.		E2 reaction
2.		E2 reaction
3.	CH3CH2CH2OH	E1 reaction
4.		E1cb reaction

Which one of the following pairs is correctly matched?

(1)  E1cb reaction, Hofmann elimination

(2) Hofmann rule, most substituted alkene

(3) Saytzeff rule, least substituted alkene

(4) E1 reaction, Hofmann elimination

Arrange the reactivity of alcohols in decreasing order for E1 elimination reaction:

(i) $OH$
$l$
$C{H}_3-CH-C{H}_3$

(ii) $OH$
$l$
$C{H}_3-C-C{H}_3$
$l$
$C{H}_3$

(iii) $OH$
$l$
$C_6{H}_5-C-C{H}_3$
$l$
$C{H}_3$

(iv) $C{H}_3-C{H}_2-C{H}_{2}OH$

Select the correct answer from the codes given below:

Codes:

1. (iii), (ii), (iv), (i)

2. (ii), (iii), (iv), (i)

3. (ii), (iii), (i), (iv)

4. (iii), (ii), (i), (iv)