EMF of Daniell cell was found using different concentrations of Zn2+ion. A graph was then plotted between Ecell and log\(\frac{[Zn^{2+}]}{[Cu^{2+}]}\). The plot was found to be linear with an intercept of \(E_{cell}\) axis equal to 1.10 V. Ecell for Zn/Zn2+ (0.1 M)||Cu2+(0.01 M)| Cu will be:
 
1. 1.10 V
2. 1.0705 V
3. 0.93 V
4. 0.078 V

 

Subtopic:  Electrolytic & Electrochemical Cell | Nernst Equation |
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Which of the following process is not responsible for the presence of electric charge on the sol particles?
 

1.  Electron capture by sol particles
2.  Adsorption of ionic species from solution
3.  Formation of Helmholtz electrical double layer
4.  Absorption of ionic species from solution

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The thermal decomposition of HCOOH is a first order reaction with a rate constant of 2.4×10-3s-1 at certain temperature. Calculate how long will it take for three fourths of initial quantity of HCOOH to decompose?
 
1.  578 s

 


When a graph is plotted for log k vs \(\frac{1}{T}\)a straight line with a slope -6670 K is obtained. The activation energy for this reaction will be:
(R = 8.314 JK-1mol-1).
Subtopic:  Arrhenius Equation |
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The statement among the following that is not correct about the order of a reaction is:

1.  The order of a reaction can be a fractional number.
2.  The order of a reaction is an experimentally determined quantity.
3.  The order of a reaction is always equal to the sum of the stoichiometric coefficients of reactants in
the balanced chemical equation for a reaction.
4.  The order of a reaction is the sum of the powers of molar concentrations of the reactants in the rate law expression.
Subtopic:  Definition, Rate Constant, Rate Law |
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