The decomposition of a gaseous compound yields the following information:

Initial pressure, atm 1.6 0.8 0.4
Time for 50 % reaction, min 80 113 160
The order of the reaction will be:
1. 1.0 2. 1.5
3. 2.0 4. 0.5

Subtopic:  Definition, Rate Constant, Rate Law |
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For a given reaction the concentration of the reactant plotted against time gave a straight line with negative slope.

The order of the reaction will be:

1. 3                                                      

2. 2

3. 1                                                      

4. 0

Subtopic:  Order, Molecularity and Mechanism |
 65%
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The relationship between temperature and the variance in reaction rate is:

1.  2.
3. 4.
Subtopic:  Arrhenius Equation |
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If a reaction A + B  C is exothermic to the extent of 30 kJ/mol and the forward reaction has an activation energy of 70 kJ/mol, the activation energy for the reverse reaction will be:

1. 30 kJ/mol                                       

2. 40kJ/mol

3. 70 kJ/mol                                       

4. 100 kJ/mol

Subtopic:  Arrhenius Equation |
 74%
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A first-order reaction takes 40 min for 30 % decomposition. The t1/2 for this reaction will be:

1. 77.7 min 2. 27.2 min
3. 55.3 min 4. 67.3 min
Subtopic:  First Order Reaction Kinetics |
 60%
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The half-life period for a first-order reaction is 20 minutes. The time required to change the concentration of the reactants from 0.08 M to 0.01 M will be:

1. 20 minutes 2. 60 minutes
3. 40 minutes 4. 50 minutes
Subtopic:  First Order Reaction Kinetics |
 82%
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The kinetic data for the reaction: 2A + B2 → 2AB are as given below

[A]/mol L-1 [B2]/mol L-1 Rate/mol L-1s-1
0.5 1.0 2.5 × 10-3
1.0 1.0 5.0 × 10-3
0.5 2.0 1 × 10-2

The order of reaction with respect to A and B2 is, respectively:

1. 1 and 2 2. 2 and 1
3. 1 and 1 4. 2 and 2
Subtopic:  Order, Molecularity and Mechanism |
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The rate constant, the activation energy, and the Arrhenius parameter of a chemical reaction at 25°C are 3.0×10-4 s-1104.4 kJ mol-1 and 6.0×1014s-1 respectively.
The value of the rate constant as T → ∞ will be:

1. 2.0 × 1018 s-1                                                  

2. 6.0 × 1014 s-1

3.                                                                    

4. 3.6 × 1030 s-1

Subtopic:  Arrhenius Equation |
 73%
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The gas phase decomposition 2N2O5 → 4NO2 + O2 follows the first order rate law, K = 7.5 × 10-3 sec-1. The initial pressure of N2O5 is 0.1 atm. The time of decomposition of N2Oso that the total pressure becomes 0.15 atm will be -

1. 54 sec 2. 5.4 sec
3. 3.45 sec 4. 34.55 sec
Subtopic:  First Order Reaction Kinetics |
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If in the fermentation of sugar in an enzymatic solution that is 0.12 M, the concentration of the sugar is reduced to 0.06 M in 10 h and to 0.03 M in 20 h, the order of the reaction will be:

1. 1                                                   

2. 2

3. 3                                                   

4. 0

Subtopic:  First Order Reaction Kinetics |
 65%
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