A solution containing 30 g of non-volatile solute in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2.9 kPa at 298 K. The vapour pressure of water at 298 K will be -

1) 1.53 kPa

2) 2.53 kPa

3) 3.53 kPa

4) 4.53 kPa

Two elements A and B form compounds having formula AB₂ and AB₄. When dissolved in 20 g of benzene (C₆H₆), 1 g of AB₂ lowers the freezing point by 2.3 K whereas 1.0 g of AB₄ lowers it by 1.3 K. The atomic masses of A and B are respectively -

(K_f for benzene is 5.1 K kg mol^-1)

1. 15.59 u and 52.64 u

2. 25.59 u and 42.64 u

3. 13.59 u and 52.64 u

4. 23.59 u and 32.64 u

The type of inter molecular interactions present in

The insoluble compound in water is /are

1. Phenol

2. Formic acid and toluene

3. Phenol and toluene 

4. Toluene and chloroform

If the solubility product of CuS is 6 × 10^–16, the maximum molarity of CuS in an aqueous solution will be

The mass percentage of aspirin (C₉H₈O₄) in acetonitrile (CH₃CN) when 6.5 g of C₉H₈O₄ is dissolved in 450 g of CH₃CN will be:

Nalorphene (C₁₉H₂₁NO₃), similar to morphine, is used to combat withdrawal symptoms in narcotic users. The dose of nalorphene generally given is 1.5 mg.

Calculate the mass of 1.5 × 10⁻³m aqueous solution required for the above dose.

The amount of benzoic acid (C₆H₅COOH) required for preparing 250 mL of 0.15 M solution in methanol is -

The depression in the freezing point of water when 10 g of CH₃CH₂CHClCOOH is added to 250 g of water will be -

 (K_a = 1.4 × 10^–3, K_f = 1.86 K kg mol^-1)

1. 0.32 K

2. 2.87 K

3. 0.65 K

4. 5.03 K

19.5 g of CH₂FCOOH is dissolved in 500 g of water. The van’t Hoff factor and dissociation constant of fluoroacetic acid will be respectively -

($∆{\mathrm{T}}_{\mathrm{f}}$ = 1.00 K )

1) 20.75 , 4.77 x 10^-3

2) 1.075 ,  4.77 x 10^-2

3) 2.073 , 3.07 x 10^-4

4) 1.075 , 3.07 x 10^-3