The pair having only molecular solids among the following is -

1. Brass and SiC

2. Ammonium phosphate (NH4)3PO4

3. SiC and plastic 

4. Tetra phosphorus decaoxide (P4O10) and I2

Subtopic:  Introduction & Crystal System |
 67%
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Niobium crystallizes in body-centred cubic structure. If the density is 8.55 g cm−3, the atomic radius of niobium (atomic mass 93 u) is -

1. 13.32 nm

2. 12.32 nm

3. 14.32 nm

4. 15.32 nm

Subtopic:  Density & Packing Fraction |
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(i) Ge is doped with In

(ii) Si is doped with B. 

The semiconductors formed in the above cases are :

1. (i) n-type semiconductor  (ii) p-type semiconductor .

2. (i) p-type semiconductor  (ii) n-type semiconductor .

3. p-type semiconductor in both the cases.

4. n-type semiconductor in both the cases.

Subtopic:  Imperfections in Solids & Semiconductors |
 66%
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Select the correct option based on statements below:

Assertion (A): Semiconductors are solids with conductivities in the range from 10-6 — 10ohm-1 m-1.
Reason (R): Intermediate conductivity in semiconductors is due to a partially filled valence band.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.

Subtopic:  Imperfections in Solids & Semiconductors |
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Match the type of packing given in Column I with the items given in Column II.

Column I Column II
A. Square close packing in two dimensions 1. Triangular voids
B. Hexagonal close packing in two dimensions 2. Pattern of spheres is repeated in every fourth layer
C. Hexagonal close packing in three dimensions 3. Coordination number = 4
D. Cubic close packing in three dimensions 4. Pattern of sphere is repeated in alternate layers

Codes

A B C D
1. 3 2 4 1
2. 1 2 3 4
3. 3 1 4 2
4. 4 1 3 2
Subtopic:  Voids, Radius Ratio & Coordination Number |
 66%
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Match the items given in Column I with the items given in Column II.

Column I Column II
A. Mg in solid state 1p-type semiconductor
B. MgCl2 in molten state 2n-type semiconductor
C. Silicon with phosphorus 3. Electrolytic conductors
D. Germanium with boron 4. Electronic conductors

Codes

A B C D
1. 2 3 4 1
2. 1 2 3 4
3. 1 4 3 2
4. 4 3 2 1

Subtopic:  Imperfections in Solids & Semiconductors |
 86%
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Match the types of defects given in Column I with the statement given in Column II.

Column I Column II
A. Impurity defect 1. NaCl with anionic sites called F-centres
B. Metal excess defect 2. FeO with Fe3+
C. Metal deficiency defect 3. NaCl with Sr2+ and some cationic sites vacant

Codes

A B C
1. 2 3 1
2. 3 1 2
3 1 2 3
4. 2 1 3
Subtopic:  Imperfections in Solids & Semiconductors |
 73%
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Match the defects given in Column I with the statements given in Column II.

Column I Column II
A. Simple vacancy defect 1. Shown by non-ionic solids and increases the density of the solid
B. Simple interstitial defect 2. Shown by ionic solids and decreases the density of the solid
C. Frenkel defect 3. Shown by non-ionic solids and decreases the density of the solid
D. Schottky defect 4. Shown by ionic solids and density of the solid remains the same

Codes

A B C D
1. 3 1 4 2
2. 1 2 3 4
3. 1 4 3 2
4. 4 1 3 2

Subtopic:  Imperfections in Solids & Semiconductors |
 82%
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Correct statement among the following regarding conductivity in solids is -

1.   κmetals  κinsulators < κsemiconductors

2.   κmetals  κinsulators < κsemiconductors

3.   κmetals , κsemiconductors > κinsulators = zero

4.  κmetals < κsemiconductors > κinsulators  zero

Subtopic:  Imperfections in Solids & Semiconductors |
 69%
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The correct order of the packing efficiency in different types of unit cells is-

1.  Fcc < Bcc < Simple cubic

2.  Fcc > Bcc > Simple cubic

3.  Fcc < Bcc > Simple cubic

4.  Bcc < Fcc > Simple cubic

Subtopic:  Density & Packing Fraction |
 86%
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