Which of the following compounds is anti-aromatic?
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Which of the following compounds gives the maximum percentage of meta-substituted
product upon nitration with concentrated HNO₃/H₂SO₄?
1. Toluene
2. Aniline
3. Benzene
4. Isopropylbenzene
What is the role of AlCl₃ in a Friedel-Crafts reaction?
1. Absorbs HCl
2. Releases HCl
3. Generates an electrophile
4. Generates a nucleophile
n-Butylbenzene on oxidation with hot alkaline KMnO4 gives:
| 1. | Benzoic acid | 2. | Butanoic acid |
| 3. | Benzyl alcohol | 4. | Benzaldehyde |
Which of the following compounds undergoes bromination of its aromatic ring (electrophilic aromatic substitution) at the fastest rate?
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1.
2. Cl-
3. Cl
4. Cl2+
(A) C8H10 (B) C8H6O4 C8H5BrO4 (C) (one-product only)
The structure of A in the above-mentioned reaction is:
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The product (B) in the above-mentioned reaction is:
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Cyclopentadiene is much more acidic than cyclopentane, because:
| 1. | Cyclopentadiene has conjugated double bonds. |
| 2. | Cyclopentadiene has both sp2 and sp3 hybridized carbon atoms. |
| 3. | Cyclopentadiene is a strain-free cyclic system. |
| 4. | Cyclopentadienyl anion ion, the conjugate base of cyclopentadiene, is an aromatic species and hence has higher stability. |
The compounds among the following that can be generated by Friedel craft acylation is/are:
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| 1. | II, III and IV | 2. | I, III and IV |
| 3. | I and II | 4. | II and III |