What is true for a cyclic process:

a. W = 0
b. ∆E = 0
c. ∆H = 0
d. ∆E ≠ 0


1.  a, b
2.  b, c
3.  c, d
4.  a, d

Subtopic:  Enthalpy & Internal energy |
 70%
From NCERT
AIPMT - 1999
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If a system is expanded under adiabatic process, then:

1.  Temperature increases
2.  ∆E decreases
3.  ∆E increases
4.  None of the above

Subtopic:  Enthalpy & Internal energy |
 61%
From NCERT
AIPMT - 1999
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Which of the following is true for a reaction in which all the reactants & products are liquids:
1.  ∆H = ∆E
2.  ∆H = ∆W
3.  ∆H > ∆E
4.  None of the above

Subtopic:  Enthalpy & Internal energy |
 82%
From NCERT
AIPMT - 1999
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Considering entropy (S) as a thermodynamic parameter, the criterion for the spontaneity of any process is:

1. ΔSsystem ΔSsurrounding >0

2. ΔSsystem >0 only 

3. ΔSsurroundings >O only

4. ΔSsystem +ΔSsurrounding >0

Subtopic:  Spontaneity & Entropy |
 79%
From NCERT
AIPMT - 2004
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The standard enthalpy and standard entropy changes for the oxidation of ammonia at 298 K are –382.64 kJ mol–1 and –145.6 JK–1 mol–1, respectively. Standard Gibbs energy change for the same reaction at 298 K is:

1. –339.3 kJ mol–1

2. – 439.3 kJ mol–1

3. –523.2 kJ mol–1

4. –221.1 kJ mol–1

Subtopic:  Gibbs Energy Change |
 66%
From NCERT
AIPMT - 2004
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The work done during the expansion of a gas from a volume of 4 dm3 to 6 dm3 against a constant external pressure of 3 atm is:

1. –608 J

2. +304 J

3. –304 J

4. –6 J 

Subtopic:  First Law of Thermodynamics |
 76%
From NCERT
AIPMT - 2004
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2Zn+O22ZnO    G°=-616 J
2Zn+S22ZnS     G°=-293 J
S2+2O22SO2     G°=-408J

G° for the following reaction is:

2ZnS+3O22ZnO+2SO2

1. -731 J 2. -1317 J
3. -501 J 4. +731 J
Subtopic:  Gibbs Energy Change | Thermochemistry |
 79%
From NCERT
AIPMT - 2000
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At 27ºC latent heat of fusion of a compound is 2930 J/mol. Entropy change is:

1. 9.77 J/mol K

2. 10.77 J/mol K

3. 9.07 J/mol K

4. 0.977 J/mol K

Subtopic:  Spontaneity & Entropy |
 84%
From NCERT
AIPMT - 2000
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For the reaction
C2H5OH(l) + 3O2(g) →2CO2(g) + 3H2O(l) which one is true:

1. ∆H = ∆E – RT 2. ∆H = ∆E + RT
3. ∆H = ∆E + 2RT 4. ∆H = ∆E – 2RT
Subtopic:  Enthalpy & Internal energy |
 84%
From NCERT
AIPMT - 2000
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Unit of entropy is:

1. JK–1 mol–1

2. J mol–1

3. J–1K–1 mol–1

4. JK mol–1

Subtopic:  Spontaneity & Entropy |
 87%
From NCERT
AIPMT - 2002
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Hints