Q. No.1. \(\Delta H_\text{mix}\)
2. \(\Delta S_\text{mix}\)
3. \(\Delta V_\text{mix}\)
4. \(\Delta P\)
Colligative properties are dependent on which of the following factors?
| 1. | The nature of the solute particles dissolved in the solution. |
| 2. | The number of solute particles in the solution. |
| 3. | The physical properties of the solute particles dissolved in the solution. |
| 4. | The nature of solvent particles. |
A solution containing 10 g/dm3 of urea (molecular mass = 60 g mol-1) is isotonic with a 5 % solution of a non-volatile solute. The molecular mass of this non-volatile solute is:
| 1. | 25 g mol-1 | 2. | 300 g mol-1 |
| 3. | 350 g mol-1 | 4. | 200 g mol-1 |
The electrolyte having the same value of Van't Hoff factor (i) as that of Al2(SO4)3 (if all are 100% ionized) is:
| 1. | K2SO4 | 2. | K3[Fe(CN)6] |
| 3. | Al(NO3)3 | 4. | K4[Fe(CN)6] |
Consider the following statements about the composition of the vapour over an ideal 1:1 molar mixture of benzene and toluene. The correct statement is:
Assume that the temperature is constant at 25 oC.
(Given, vapour pressure data at 25 °C, benzene = 12.8 kPa, toluene = 3.85 kPa)
| 1. | The vapour will contain a higher percentage of toluene. |
| 2. | The vapour will contain equal amounts of benzene and toluene. |
| 3. | Not enough information is given to make a prediction. |
| 4. | The vapour will contain a higher percentage of benzene. |
| List-I (Equilibrium Process) |
List-II (Physical Properties) |
||
| A. | \(Liquid \rightleftharpoons Vapour\) | I. | Melting point |
| B. | \(Solid \rightleftharpoons Liquid\) | II. | Boiling point |
| C. | \(Solid \rightleftharpoons Vapour\) | III. | Sublimation point |
| D. | \(\small {Solute (solid) \rightleftharpoons Solute (solution)}\) | IV. | Saturated solution |
| V. | Unsaturated solution |
1. A-II, B-I, C-III, D-IV
2. A-I, B-II, C-III, D-IV
3. A-III, B-II, C-I, D-IV
4. A-II, B-I, C-III, D-V
Which of the following statements is correct regarding the behaviour of an aqueous solution of hydrochloric acid (HCl)?
1. Obeys Raoult's law
2. Shows negative deviations from Raoult's law
3. Shows positive deviations from Raoult's law
4. Obeys Henry's law at all compositions
| Type of solution | Example | ||
| a. | Solid in gas | i. | Aerated water |
| b. | Gas in liquid | ii. | Smoke |
| c. | Liquid in solid | iii. | Solution of hydrogen in palladium |
| d. | Gas in solid | iv. | Amalgams |
| a | b | c | d | |
| 1. | i | iii | iv | ii |
| 2. | ii | i | iv | iii |
| 3. | iii | i | iv | ii |
| 4. | iv | i | ii | iii |
The solubility of gases in liquids generally decreases as temperature increases.
The primary reason for this behavior is:
| 1. | Dissolution of a gas in a liquid is an endothermic process. |
| 2. | Dissolution of a gas in a liquid is an exothermic process. |
| 3. | Gases are highly compressible. |
| 4. |
All of the above statements are correct. |
| List-I (Types of Solutions) |
List-II (Common Examples) |
||
| A. | Gas in Gas | I. | Solution of hydrogen in palladium |
| B. | Solid in Gas | II. | Mixture of oxygen and nitrogen gas |
| C. | Gas in Liquid | III. | Camphor in nitrogen gas |
| D. | Gas in Solid | IV. | Oxygen dissolved in water |
| Options: | A | B | C | D |
| 1. | II | III | IV | I |
| 2. | II | I | IV | III |
| 3. | II | IV | III | I |
| 4. | II | IV | I | III |
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