The formation of the oxide ion O2– (g), from the oxygen atom requires first an exothermic and then an endothermic step as shown below,
O(g)+e-→O-; ∆fH0=–141 kJ mol-1
O-(g)+e-→O2-(g); ∆fH0=+780 kJ mol-1
Thus, the process of formation of O2– in the gas phase is unfavorable even though O2– is isoelectronic with neon. It is due to the fact that:
1. | Electron repulsion outweighs the stability gained by achieving noble gas configuration. |
2. | O– ion has a comparatively smaller size than the oxygen atom. |
3. | Oxygen is more electronegative. |
4. | Addition of electrons in oxygen results in a large size of the ion. |
The species Ar, K+ and Ca2+ contain the same number of electrons. In which order do their radii increase?
1. Ar < K+ < Ca2+
2. Ca2+ < Ar < K+
3. Ca2+ < K+ < Ar
4. K+ < Ar < Ca2+
The correct order of ionic radii is:
1. H->H+>H
2. Na+>F->O2-
3. F->O2->Na+
4. N3->Mg2+>Al3+
Which ion is isoelectronic with Be²⁺?
1. H+
2. Li+
3. Na+
4. Mg2+
The value of electron gain enthalpy of Na+, if IE1 of Na = 5.1 eV, is:
1. +10.2 eV
2. –5.1 eV
3. –10.2 eV
4. +2.55 eV
The correct order of the decreasing ionic radii among the following isoelectronic species is:
1. Ca2+>K+>S2->Cl-
2. Cl->S2->Ca2+>K+
3. S2->Cl->K+>Ca2+
4. K+>Ca2+>Cl->S2-
The correct order of increasing electron affinity for the elements, O, S, F and Cl is:
1. | Cl < F < O < S | 2. | O < S < F < Cl |
3. | F < S < O < Cl | 4. | S < O < Cl < F |
Among the elements Ca, Mg, P and Cl, the correct order of increasing atomic radii is:
1. Cl < P < Mg < Ca
2. P < Cl < Ca < Mg
3. Ca < Mg < P < Cl
4. Mg < Ca < Cl < P
Amongst the elements with the following electronic configurations, which one of them may have the highest ionisation energy?
1. [Ne] 3s2 3p3
2. [Ne] 3s2 3p2
3. [Ar] 3d10 4s2 4p3
4. [Ne] 3s2 3p1