The conductivity of 0.00241 M acetic acid is 7.896 × 10–5 S cm–1. If for acetic acid is 390.5 S cm2 mol–1, the dissociation constant will be
1. \(2.45 \times 10^{-5} \mathrm{~mol} \ \mathrm{~L}^{-1} \)
2. \(1.86 \times 10^{-5} \mathrm{~mol} \ \mathrm{L^{-1}} \)
3. \(3.72 \times 10^{-5}\mathrm{~mol} \mathrm{~L^{-1}} \)
4. \(2.12 \times 10^{-5}\mathrm{~mol} \mathrm{~L^{-1}}\)
The resistance of a cell containing 0.001 M KCl solution at 298 K is 1500 Ω. The conductivity is 0.146 × 10–3 S cm–1. The cell constant would be-
1. | 2. | ||
3. | 4. |
The amount of charge required for the reduction of 1 mol of to is -
The number of Faradays required to produce 20.0 g of Ca from molten CaCl2 is-
1. 2F
2. 1F
3. 4F
4. 3F
Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3, and CuSO4, respectively are connected in series.
A steady current of 1.5 amperes was passed through them until 1.45 g of silver was deposited at the cathode of cell B. The current flow time is-
1. 14 minutes
2. 25 minutes
3. 20 minutes
4. 11 minutes
Mg(s) | Mg2+(0.001M) || Cu2+(0.0001 M) | Cu(s)
The value of for the above reaction is -
1. | 3.46 V | 2. | 3.15 V |
3. | 2.67 V | 4. | 1.24 V |
Given the standard electrode potentials:
K+/K = –2.93 V |
Ag+/Ag = 0.80 V |
Hg2+/Hg = 0.79 V |
Mg2+/Mg = –2.37 V |
Cr3+/Cr = – 0.74 V |
1. | Cr < Mg < K < Ag < Hg | 2. | Mg < K < Ag < Hg < Cr |
3. | K < Ag < Hg < Cr < Mg | 4. | Ag < Hg < Cr < Mg < K |
The correct statement about the given galvanic cell equation is -
Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s)
1. | The current will flow from silver to zinc in the external circuit. |
2. | The current will flow from zinc to silver in the external circuit. |
3. | The current will flow from silver to zinc in the internal circuit. |
4. | The current will flow from zinc to silver in the internal circuit. |
2Cr(s) + 3Cd2+(aq) → 2Cr3+(aq) + 3Cd
;
The value of in the above reaction will be-
1. | -196.83 kJ
|
2. | 196.83 kJ
|
3. | 186.83 kJ
|
4. | -186.83 kJ |
The incorrect statement(s) among the below is/are:
(a) | The unit of conductivity is S cm–2 |
(b) | Specific Conductivity of weak and strong electrolytes always decreases with a decrease in concentration. |
(c) | The unit of molar conductivity is S cm2 mol–1 |
(d) | Molar conductivity increases with an increase in concentration. |
1. Only (a)
2. (a) and (d)
3. (b) and (d)
4. (a) and (c)