Match the following equilibria with the corresponding condition.
A. | Liquid ⇌ Vapour | I. | Saturated solution |
B. | Solid ⇌ Liquid | II. | Boiling point |
C. | Solid ⇌ Vapour | III. | Sublimation point |
D. | Solute (s) ⇌ Solute (solution) | IV. | Melting point |
V | Unsaturated solution |
Codes:
A | B | C | D | |
1. | II | IV | III | I |
2. | I | II | III | V |
3. | V | IV | III | II |
4. | IV | V | III | II |
Column I (Reaction) | Column II (Equilibrium constant) |
A. 2N2(g)+6H2(g)⇌4NH3(g) | 1. 2Kc |
B. 2NH3(g)⇌N2(g)+3H2(g) | 2. K1/2c |
C. 12N2(g)+32H2(g)⇌NH3(g) | 3. 1Kc |
4. K2c |
Codes:
A | B | C | |
1. | 4 | 3 | 2 |
2. | 1 | 2 | 3 |
3. | 1 | 4 | 3 |
4. | 4 | 1 | 3 |
Match the standard free energy of the reaction with the corresponding equilibrium constant.
A. ∆G⊝>0 | 1. K>1 |
B. ∆G⊝<0 | 2. K=1 |
C. ∆G⊝=0 | 3. K=0 |
4. K<1 |
Codes:
A | B | C | |
1. | 4 | 1 | 2 |
2. | 1 | 2 | 3 |
3. | 2 | 4 | 3 |
4. | 4 | 1 | 3 |
Match the following species with the corresponding conjugate acid:
Species | Conjugate acid |
A. NH3 | 1. CO2-3 |
B. HCO-3 | 2. NH+4 |
C. H2O | 3.H3O+ |
D. HSO-4 | 4. H2CO3 |
5. H2SO4 |
Codes
A | B | C | D | |
1. | 2 | 5 | 1 | 5 |
2. | 2 | 4 | 3 | 5 |
3. | 5 | 4 | 3 | 2 |
4. | 4 | 5 | 3 | 2 |
Match Column-I with Column-II and mark the appropriate option:
Column-I (Term) |
Column-II (Conditions) |
||
(A) |
Equilibrium |
(i) |
∆G>0,K<1 |
(B) |
Spontaneous reaction |
(ii) |
∆G=0 |
(C) |
Non-spontaneous reaction |
(iii) |
∆G<0,K>1 |
Codes:
Options: | A | B | C |
1. | (ii) | (iii) | (i) |
2. | (i) | (ii) | (iii) |
3. | (ii) | (i) | (iii) |
4. | (iii) | (i) | (ii) |
Given below are two statements:
Assertion (A): | The increasing order or acidity of hydrogen halides is HF<HCI<HBr<HI. |
Reason (R): | While comparing acids formed by the elements belonging to the same group of the periodic table, H-A bond strength is a more important factor in determining the acidity of an acid than the polar nature of the bond. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Given below are two statements:
Assertion (A): | A solution containing a mixture of acetic acid and sodium acetate maintains a constant value of pH on the addition of small amounts of acid or alkali. |
Reason (R): | A solution containing a mixture of acetic acid and sodium acetate acts as a buffer solution. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Given below are two statements:
Assertion (A): | The ionisation of hydrogen sulphide in water is low in the presence of hydrochloric acid. |
Reason (R): | Hydrogen sulphide is a weak acid. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Assertion (A): | For any chemical reaction at a particular temperature, the equilibrium constant is fixed and is a characteristic property. |
Reason (R): | Equilibrium constant is independent of temperature. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Given below are two statements:
Assertion (A): | An aqueous solution of ammonium carbonate is basic. |
Reason (R): |
The acidic or basic nature of a salt solution of a salt of a weak acid and a weak base depends on the Ka and Kb values of the acid and the base forming it. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |