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An aqueous solution contains 0.10 M H2S and 0.20 M HCl. If the equilibrium constant for the formation of HS from H2S is 1.0 × 10–7 and that of S2– from HS ions is 1.2 × 10–13 then the concentration of S2– ions in aqueous solution will be:

1. 5 × 10–8 M

2. 3 × 10–20 M

3. 6 × 10–21 M

4. 5 × 10–19 M

Subtopic:  Ionisation Constant of Acid, Base & Salt |
 62%
Level 2: 60%+
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For a weak acid HA with a degree of dissociation x, which of the following gives the correct expression for \((\text{pH} - \text{pKa})\)?
1. log (1+2x) 2. \(\log \left(\dfrac{1-x}{x}\right)\)
3. 0 4. \(\log \left(\dfrac{x}{1-x}\right)\)
Subtopic:  Ionisation Constant of Acid, Base & Salt |
 61%
Level 2: 60%+
JEE
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