| Statement I: | At 20 °C, the molality of KCl solution is 'X' m, and on decreasing temperature to -10 °C molality remains unchanged. |
| Statement II: | On changing temperature mass remains unchanged. |
| 1. | Both Statement I and Statement II are True. |
| 2. | Both Statement I and Statement II are False. |
| 3. | Statement I is True, and Statement II is False. |
| 4. | Statement I is False, and Statement II is True. |
The values of van’t Hoff factors for KCl, NaCl and K2SO4 respectively are:
| 1. | 2, 2 and 2 | 2. | 2, 2 and 3 |
| 3. | 1, 1 and 2 | 4. | 1, 1 and 1 |

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What is the van’t Hoff factor for a very dilute solution of \(Fe_
2
(SO_
4)_
3\) ?
1. 9
2. 5
3. 2
4. 6
Which one of the following electrolytes has the same value of van't Hoff's factor(i) as that of Al2(SO4)3 (if all are 100% ionised)?
1. K2SO4
2. K3[Fe(CN)6]
3. Al(NO3)3
4. K4[Fe(CN)6]

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The degree of dissociation of a weak electrolyte, AxBy is related to van't Hoff factor (i) by the expression :
1.
2.
3.
4.
| Assertion (A): | The value of Van't Hoff factor (i) for ethanoic acid in benzene is less than unity. |
| Reason (R): | Molecules of ethanoic acid dimerizes in benzene due to hydrogen bonding. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |
| 1. | 1.0 M NaOH | 2. | 1.0 M \(Na_2SO_4~~~~~~\) |
| 3. | 1.0 M \(NH_4NO_3~~~~\) | 4. | 1.0 M KNO3 |