Complexes with halide ligands are generally:

1. High spin complexes.

2. Low spin complexes.

3. Both high spin and low spin complexes.

4. None of the above.

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If 1/3rd of the total chlorine of the compound is precipitated by adding AgNO3 to its aqueous solution, then the most likely structure of CrCl3.6H2O among the following is:

1. CrCl3.6H2O 2. [Cr(H2O)3Cl3](H2O)3
3. [CrCl2(H2O)4]Cl.2H2O 4. [CrCl.(H2O)5]Cl2.H2O
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The correct statement among the following is:

1. If ∆0 < P, low spin state is more stable.
2. CO is a very weak ligand.
3. The colour of a complex depends only on the nature of the metal ion.
4. CO is a weak base but a strong ligand.
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The complex that does not have a tetrahedral shape is:

1. CuNH342+             

2. Ni(CO)4

3. NiCl42-                     

4. ZnNH342+

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The complex that contains only one unpaired electron is:

1. [CoF6]3-

2. [Co(C2O4)3]3-

3. [Fe(CN)6]3-

4. [MnCl6]3-

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Total geometrical isomers possible for [Pd2+(NH2-CH(CH3)-CO2-)2]0 are -

1. 2

2. 3

3. 4

4. 6

Subtopic:  Isomerism in Coordination Compounds |
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Isomerism exhibited by [Co(EDTA)]- is/are:
 

1. Optical & geometrical isomerism.

2. Geometrical isomerism.

3. Optical isomerism.

4. No isomerism is exhibited by [Co(EDTA)]-

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Find the total number of possible coordination isomers for each of the following compounds:
  1. [Co(en)₃][Cr(C₂O₄)₃]
  2. [Cu(NH₃)₄][CuCl₄]
  3. [Ni(en)₃][Co(NO₂)₆]
1. 4, 4, 4 2. 2, 2, 2
3. 2, 2, 4 4. 4, 2, 4
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Which of the following complex ions is Bronsted-Lowry acid?

1. [Cu(NH3)4]2+

2. [FeCl4]-

3. [Fe(H2O)6]3+

4. [Zn(OH)4]2-

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The expected number of unpaired electrons for the complex ion [Cr(NH3)6]3+ are: 

1. 2

2. 3

3. 4

4. 5

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