Match the reagents from List-I with the corresponding radicals from List-II and choose the correct option:
List-I (Reagent) List-II (Radical)
(i)  \(\text { dil. } \mathrm{HCl}\) (A)  Pb2+
(ii)  \(\begin{aligned} & \mathrm{NH}_4 \mathrm{Cl}+\mathrm{NH}_4 \mathrm{OH}+ \\ & \left(\mathrm{NH}_4\right)_2 \mathrm{CO}_3 \end{aligned}\) (B)  Al3+
(iii)  \(\mathrm{NH}_4 \mathrm{Cl}+\mathrm{NH}_4 \mathrm{OH}+\mathrm{H}_2 \mathrm{~S}\) (C)  Mn2+
(iv)  \(\mathrm{NH}_4 \mathrm{Cl}+\mathrm{NH}_4 \mathrm{OH}\) (D)  Sr2+
 
1. (i)-(A), (ii)-(D), (iii)-(C), (iv)-(B)
2. (i)-(D), (ii)-(A), (iii)-(C), (iv)-(B)
3. (i)-(A), (ii)-(D), (iii)-(B), (iv)-(C)
4. (i)-(B), (ii)-(C), (iii)-(D), (iv)-(A)
Subtopic:  Detection of Cations |
 67%
Level 2: 60%+
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Which of the following cations will turn a borax bead green when heated in a reducing (luminous) flame?

1. \(\mathrm{Fe^{3+}}\) 2. \(\mathrm{Cu^{2+}}\)
3. \(\mathrm{Mn^{2+}}\) 4. \(\mathrm{Ni^{2+}}\)
Subtopic:  Detection of Cations |
Level 3: 35%-60%
JEE
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Identify the inorganic sulphides that are yellow in colour:
(A) (NH4)2S
(B) PbS
(C) CuS
(D) As2S3
(E) As2S5

Choose the correct answer from the options given below:
1. (A) and (C) only
2. (A), (D) and (E) only
3. (A) and (B) only
4. (D) and (E) only
Subtopic:  Detection of Cations |
Level 4: Below 35%
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Identify A, B and C in the given below reaction sequence:

1. PbCl2 , PbSO4 , PbCrO4
2. PbS, PbSO4 , PbCrO4
3. PbS, PbSO4 , Pb(CH3COO)2
4. PbCl2 , Pb(SO4)2 , PbCrO4
Subtopic:  Detection of Cations |
Level 3: 35%-60%
JEE
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When borax is heated with CoO on a platinum loop, blue coloured bead formed is largely due to:
1. \(\mathrm{B}_2 \mathrm{O}_3\)
2. \(\mathrm{Co}\left(\mathrm{BO}_2\right)_2\)
3. \(\mathrm{CoB}_4 \mathrm{O}_7\)
4. \(\mathrm{Co}\left[\mathrm{B}_4 \mathrm{O}_5(\mathrm{OH})_4\right]\)
Subtopic:  Detection of Cations |
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Match List-I with List-II:
List-I
(Metal Ion)
List-II
(Group in Qualitative analysis)
(a) \(Mn^{2+}\) (i) Group-III
(b) \(As^{3+}\) (ii) Group-IIA
(c) \(Cu^{2+}\) (iii) Group-IV
(d) \(Al^{3+}\) (iv) Group-IIB

Choose the most appropriate answer from the options given below:
1. (a)-(i), (b)-(iv), (c)-(ii), (d)-(iii)
2. (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)
3. (a)-(iv), (b)-(ii), (c)-(iii), (d)-(i)
4. (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i)
Subtopic:  Detection of Cations |
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The metal ion whose electronic configuration is not affected by the nature of the ligand and which gives a violet colour in a non-luminous flame under hot conditions in the borax bead test is:

1. \(\mathrm{Ti}^{3+}\)
2. \(\mathrm{Ni}^{2+}\)
3. \(\mathrm{Mn}^{2+}\)
4. \(\mathrm{Cr}^{3+}\)
Subtopic:  Detection of Cations |
Level 4: Below 35%
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Consider the following ions:
\(\mathrm{Cu}^{2+}, \mathrm{Fe}^{3+}, \mathrm{Ba}^{2+}, \mathrm{Ca}^{2+}, \mathrm{NH}_4^{+}, \mathrm{Mg}^{2+}, \mathrm{Zn}^{2+}\)
Among the following cations, the number of cations that will give a characteristic precipitate in their identification tests with \(\mathrm{K}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]\) is/are:
1. Zero (0) 2. Three (3)
3. Two (2) 4. Four (4)
Subtopic:  Detection of Cations | The chemistry involved in the titrimetric exercises |
Level 4: Below 35%
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