Calculate ΔG° for the following reaction:

Fe²⁺(aq) + Ag⁺(aq) → Fe³⁺(aq) + Ag(s)

Given:

E°Fe³⁺/Fe²⁺ = +0.77 V
E°Ag⁺/Ag = +0.80 V

1. +2.89 kJ

2. -2.89 kJ

3. -2.89 J

4. -186.83 J

Subtopic:  Relation between Emf, G, Kc & pH |
 84%
Level 1: 80%+
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Given:
(i) Cu2++2e-→Cu    Eo = 0.337 V 
(ii) Cu2++e-→Cu+  Eo = 0.153 V 
Electrode potential, Eo for the reaction, 
Cu++e-→Cu, will be: 

1. 0.52 V

2. 0.90 V

3. 0.30 V

4. 0.38 V

Subtopic:  Relation between Emf, G, Kc & pH |
 76%
Level 2: 60%+
AIPMT - 2009
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What is the standard cell potential (E°cell) for the reaction A(s) + 2B⁺ → A²⁺ + 2B(s), given that the equilibrium constant (Kc = equilibrium constant) is 10¹²?

1. 0.35 V 2. 0.71 V
3. 0.01 V 4. 1.36 V
Subtopic:  Relation between Emf, G, Kc & pH |
 80%
Level 1: 80%+
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What is the correct order of ionic mobility of the following ions in an aqueous solution?
1. K+> Na+> Rb+> Cs+ 2. Cs+> Rb+> K+> Na+
3. Rb+> K+> Cs+> Na+ 4. Na+> K+> Rb+> Cs+
Subtopic:  Relation between Emf, G, Kc & pH |
 73%
Level 2: 60%+
AIPMT - 2008
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The value of  ∆G°  in the reaction below would be:
\(\small{\mathrm{Zn}(\mathrm{s})+\mathrm{Ag}_2 \mathrm{O}(\mathrm{s})+\mathrm{H}_2 \mathrm{O}(\mathrm{l}) \rightarrow \mathrm{Zn}^{+2}(\mathrm{aq})+2 \mathrm{Ag}(\mathrm{s})+2 \mathrm{OH}^{-}(\mathrm{aq})}\)


Given: \(E_{cell}^{\circ} = 1.04V\)

1. –2.13 kJ

2. –21.3 kJ

3. –201 kJ

4. –31.12 kJ

Subtopic:  Relation between Emf, G, Kc & pH |
 80%
Level 1: 80%+
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A hydrogen gas electrode is made by dipping platinum wire in a solution of HCl of pH = 10 and by passing hydrogen gas around the platinum wire at one atm pressure. The oxidation potential of the electrode would be: 

1. 0.59 V 2. 0.118 V
3. 1.18 V 4. 0.059 V
Subtopic:  Relation between Emf, G, Kc & pH |
 78%
Level 2: 60%+
AIPMT - 2013
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Given the following cell reaction:
 \(\mathrm{2Fe^{3+}(aq) \ + \ 2I^{-}(aq)\rightarrow 2Fe^{2+}(aq) \ + \ I_{2}(aq)}\)

  \(E_{cell}^{o} \ = \ 0.24 \ V\) at \(298\) \(K\).
The standard Gibbs energy ∆rG⊝ of the cell reaction is:

[Given: \(F  = 96500\) \(C\) \(mol^{- 1}\)]

1. \(23 . 16\) \(kJ\) \(mol^{- 1}\)

2. \(- 46 . 32\) \(kJ\) \(mol^{- 1}\)

3. \(- 23 . 16\) \(kJ\) \(mol^{- 1}\)

4. \(46 . 32\) \(kJ\) \(mol^{- 1}\)

Subtopic:  Relation between Emf, G, Kc & pH |
 75%
Level 2: 60%+
NEET - 2019
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 2Cr(s) + 3Cd2+(aq) → 2Cr3+(aq) + 3Cd

E⊝Cr3+/Cr= -0.74 V; E⊝Cd2+/Cd=-0.40 V

The value of ∆Gro in the above reaction will be-

1. -196.83 kJ

2. 196.83 kJ

3. 186.83 kJ

4. -186.83 kJ

Subtopic:  Relation between Emf, G, Kc & pH |
 79%
Level 2: 60%+
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For a cell involving one electron \(E_{cell}^{\ominus} = 0 . 59  V\) at 298 K. The equilibrium constant for the cell reaction is :
\(\mathrm{[Given~ that~ \frac {2.303 ~RT}{F} = 0.059 ~V~ at~ T = 298 K]}\)

1. \(1 . 0 \times \left(10\right)^{30}\) 2. \(1 . 0 \times \left(10\right)^{2}\)
3. \(1 . 0 \times \left(10\right)^{5}\) 4. \(1 . 0 \times \left(10\right)^{10}\)

Subtopic:  Relation between Emf, G, Kc & pH |
 74%
Level 2: 60%+
NEET - 2019
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What happens to the pH of the solution during the electrolysis of aqueous NaCl (brine)?
1. The pH of the solution increases 2. The pH of the solution decreases
3. There is no change in the pH of the solution. 4. None of the above.
Subtopic:  Relation between Emf, G, Kc & pH |
 65%
Level 2: 60%+
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