When 4 g of iron is burnt to ferric oxide at a constant pressure, 29.28 kJ of heat is evolved.
The enthalpy of formation of ferric oxide will be-
(At. mass of Fe = 56) ?
1. 81.98 kJ
2. 819.8 kJ
3. 40.99 kJ
4. +819.8 kJ
Hydrolysis of sucrose is given by the following reaction
Sucrose + H2O Glucose + Fructose
If the equilibrium constant (Kc) is 21013 at 300 K, the value of at the same temperature will be:
1. 8.314 J mol–1 K–1300 Kln (21013)
2. 8.314 J mol–1 K–1300 Kln (31013)
3. –8.314 J mol–1 K–1300 Kln (41013)
4. –8.314 J mol–1 K–1300 Kln (21013)
The enthalpies of formation of Al2O3 and Cr2O3 are – 1596 kJ and – 1134 kJ, respectively. ∆H for the reaction 2Al + Cr2O3 → 2Cr + Al2O3 is -
1. | –1365 kJ | 2. | 2730 kJ |
3. | –2730 kJ | 4. | –462 kJ |
Assume each reaction is carried out in an open container. For which of the following reactions will
1.
2.
3.
4.
Which of the following is not an endothermic reaction?
1. Combustion of methane
2. Decomposition of water
3. Dehydrogenation of ethane or ethylene
4. Conversion of graphite to diamond
For the following given equations and values, determine the enthalpy of reaction at 298 K for the reaction-
C2H4(g) + 6F2(g) 2CF4(g) + 4HF(g)
H2(g) + F2(g) 2HF(g) = -537 kJ
C(s) + 2F2(g) CF4(g) =-680 kJ
2C(s) + 2H2(g) C2H4(g) = 52 kJ
1. -1165
2. -2486
3. +1165
4. +2486
Change in entropy is negative for:
1. Bromine (l)Bromine(g)
2. C(s) + H2O(g) CO(g) + H2(g)
3. N2(g,10 atm)N2(g,1 atm)
4. Fe ( 1mol, 400 K) Fe( 1mol, 300 K)
Entropy decreases during:
1. Crystallization of sucrose from solution
2. Rusting of iron
3. Melting of ice
4. Vaporization of camphor
A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to 375 mL at a constant temperature of 37.0ºC. As it does so, it absorbs 208 J of heat. The values of q and w for the process will be-
(R = 8.314 J/mol K) (ln 7.5 = 2.01)
1. | q = +208 J, w = -208 J | 2. | q = -208 J, w = -208 J |
3. | q = -208 J, w = + 208 J | 4. | q = +208 J, w = + 208 J |
For the reaction, , the value of ∆H and ∆S are respectively -
1.
2.
3.
4.