Q. No.The products A and B obtained in the following reactions, respectively, are
\( \begin{aligned} & 3 \mathrm{ROH}+\mathrm{PCl}_3 \rightarrow 3 \mathrm{RCl}+\mathrm{A} \\ & \mathrm{ROH}+\mathrm{PCl}_5 \rightarrow \mathrm{RCl}+\mathrm{HCl}+\mathrm{B} \end{aligned} \)
1. \(\mathrm{POCl}_3~ and~ \mathrm{H}_3 \mathrm{PO}_4 \)
2. \(\mathrm{H}_3 \mathrm{PO}_4~ and ~\mathrm{POCl}_3 \)
3. \(\mathrm{H}_3 \mathrm{PO}_3~and ~\mathrm{POCl}_3 \)
4. \(\mathrm{POCl}_3~and ~\mathrm{H}_3 \mathrm{PO}_3\)
\( \begin{aligned} & 3 \mathrm{ROH}+\mathrm{PCl}_3 \rightarrow 3 \mathrm{RCl}+\mathrm{A} \\ & \mathrm{ROH}+\mathrm{PCl}_5 \rightarrow \mathrm{RCl}+\mathrm{HCl}+\mathrm{B} \end{aligned} \)
1. \(\mathrm{POCl}_3~ and~ \mathrm{H}_3 \mathrm{PO}_4 \)
2. \(\mathrm{H}_3 \mathrm{PO}_4~ and ~\mathrm{POCl}_3 \)
3. \(\mathrm{H}_3 \mathrm{PO}_3~and ~\mathrm{POCl}_3 \)
4. \(\mathrm{POCl}_3~and ~\mathrm{H}_3 \mathrm{PO}_3\)
Subtopic: Group 15 - Preparation, Properties & Uses |
69%
From NCERT
NEET - 2024
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Match List-I with List-II:
Identify the correct answer from the option given below:
1. A- III, B-I, C-IV, D-II
2. A-I, B-IV, C-III, D-II
3. A-II, B-IV, C-I, D-II
4. A-III, B-IV, C-I, D-II
| List-I (Atom / Molecule) |
List-II (Property) |
||
| A. | Nitrogen | I. | Paramagnetic |
| B. | Fluorine molecule | II. | Most reactive element in group 18 |
| C. | Oxygen molecule | III. | Element with highest ionisation enthalpy in group 15 |
| D. | Xenon atom | IV. | Strongest oxidising agent |
Identify the correct answer from the option given below:
1. A- III, B-I, C-IV, D-II
2. A-I, B-IV, C-III, D-II
3. A-II, B-IV, C-I, D-II
4. A-III, B-IV, C-I, D-II
Subtopic: Group 18 - Preparation, Properties & Uses | Group 16 - Preparation, Properties & Uses | Group 15 - Preparation, Properties & Uses |
90%
From NCERT
NEET - 2024
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Identify the incorrect statement about \(\mathrm{PCl_5}\).
1. \(\mathrm{PCl_5}\) possesses two different \(\mathrm{Cl-P-Cl}\) bond angles.
2. All five \(\mathrm{P-Cl}\) bonds are identical in length.
3. \(\mathrm{PCl_5}\) exhibits sp3d hybridisation.
4. \(\mathrm{PCl_5}\) consists of five \(\mathrm{P-Cl}\) (sigma) bonds.
1. \(\mathrm{PCl_5}\) possesses two different \(\mathrm{Cl-P-Cl}\) bond angles.
2. All five \(\mathrm{P-Cl}\) bonds are identical in length.
3. \(\mathrm{PCl_5}\) exhibits sp3d hybridisation.
4. \(\mathrm{PCl_5}\) consists of five \(\mathrm{P-Cl}\) (sigma) bonds.
Subtopic: Group 15 - Preparation, Properties & Uses |
87%
From NCERT
NEET - 2024
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Hints
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Identify the incorrect statement.
1. \(\mathrm{PEt}_3\) and \(\mathrm{Asph}_3\) as ligands can form \(\mathrm{d} \pi-\mathrm{d} \pi\) bone with transition metals.
2. The \(\mathrm{N}-\mathrm{N}\) single bond is as strong as the \(\mathrm{P}-\mathrm{P}\) single bond.
3. Nitrogen has unique ability to form \(\mathrm{p \pi-p \pi}\) multiple bonds with nitrogen, carbon and oxygen.
4. Nitrogen cannot form \(\mathrm{d} \pi-\mathrm{p} \pi\) bond as other heavier elements of its group.
1. \(\mathrm{PEt}_3\) and \(\mathrm{Asph}_3\) as ligands can form \(\mathrm{d} \pi-\mathrm{d} \pi\) bone with transition metals.
2. The \(\mathrm{N}-\mathrm{N}\) single bond is as strong as the \(\mathrm{P}-\mathrm{P}\) single bond.
3. Nitrogen has unique ability to form \(\mathrm{p \pi-p \pi}\) multiple bonds with nitrogen, carbon and oxygen.
4. Nitrogen cannot form \(\mathrm{d} \pi-\mathrm{p} \pi\) bond as other heavier elements of its group.
Subtopic: Group 15 - Preparation, Properties & Uses |
84%
From NCERT
NEET - 2024
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The correct order for boiling points of the following compounds is:
| 1. | AsH3 > PH3 > NH3 > SbH3 > BiH3 |
| 2. | BiH3 > SbH3 > NH3 > AsH3 > PH3 |
| 3. | NH3 > PH3 > AsH3 > SbH3 > BiH3 |
| 4. | PH3 > NH3 > AsH3 > SbH3 > BiH3 |
Subtopic: Group 15 - Preparation, Properties & Uses |
63%
From NCERT
NEET - 2022
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NEET 2025 - Target Batch
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The reaction that is a part of large scale industrial preparation of nitric acid is:
| 1. | \(\mathrm{NaNO}_3+\mathrm{H}_2 \mathrm{SO}_4\xrightarrow[500~K, \ 9\text{ bar}]{Pt} \mathrm{NaHSO}_4+\mathrm{HNO}_3\) |
| 2. | \(4 \mathrm{NH}_3+5 \mathrm{O}_2 \text{(from air)}\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{NO}+6 \mathrm{H}_2 \mathrm{O}\) |
| 3. | \(4 \mathrm{HPO}_3+2 \mathrm{~N}_2 \mathrm{O}_5\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{P}_4 \mathrm{O}_{10}\) |
| 4. | \(\mathrm{Cu}\left(\mathrm{NO}_3\right)_2+2 \mathrm{NO}_2+2 \mathrm{H}_2 \mathrm{O} \\ \xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{Cu}\) |
Subtopic: Group 15 - Preparation, Properties & Uses |
61%
From NCERT
NEET - 2022
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NEET 2025 - Target Batch
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In which one of the following arrangements the given sequence is not strictly according to the properties indicated against it?
| 1. | NH3 < PH3 < AsH3 < SbH3 | Increasing acidic character |
| 2. | CO2 < SiO2 < SnO2 < PbO2 | Increasing oxidizing power |
| 3. | HF < HCl < HBr < HI | Increasing acidic strength |
| 4. | H2O < H2S < H2Se < H2Te | Increasing pKa values |
Subtopic: Group 15 - Preparation, Properties & Uses |
64%
From NCERT
NEET - 2021
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NEET 2025 - Target Batch
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Which one of the following reactions does not come under hydrolysis type reaction?
1. \(\mathrm{S i C l_{4 \left(\right. l \left.\right)} + 2 H_{2} O_{\left(\right. l \left.\right)} \rightarrow S i O_{2 \left(\right. s \left.\right)} + 4 H C l_{\left(\right. a q \left.\right)}}\)
2. \(\mathrm{L i_{3} N_{\left(\right. s \left.\right)} + 2 H_{2} O_{\left(\right. l \left.\right)} \rightarrow N H_{3 \left(\right. g \left.\right)} + 3 L i O H_{\left(\right. a q \left.\right)}}\)
3. \(\mathrm{2 F_{2 \left(\right. g \left.\right)} + 2 H_{2} O_{\left(\right. l \left.\right)} \rightarrow 4 H F_{\left(\right. a q \left.\right)} + O_{2 \left(\right. g \left.\right)}}\)
4. \(\mathrm{P_{4} O_{10 \left(\right. s \left.\right)} + 6 H_{2} O_{\left(\right. l \left.\right)} \rightarrow 4 H_{3} P O_{4 \left(\right. a q \left.\right)}}\)
Subtopic: Group 15 - Preparation, Properties & Uses |
From NCERT
NEET - 2020
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NEET 2025 - Target Batch
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Match the name of process given in Column I with the name of compound given in Column II and mark the correct option.
| Column I | Column II | ||
| (a) | Pure nitrogen | (i) | Chlorine |
| (b) | Haber process | (ii) | Sulphuric acid |
| (c) | Contact process | (iii) | Ammonia |
| (d) | Deacon's process | (iv) | Sodium azide or Barium azide |
| (a) | (b) | (c) | (d) | |
| 1. | (iv) | (iii) | (ii) | (i) |
| 2. | (i) | (ii) | (iii) | (iv) |
| 3. | (ii) | (iv) | (i) | (iii) |
| 4. | (iii) | (iv) | (ii) | (i) |
Subtopic: Group 15 - Preparation, Properties & Uses |
88%
From NCERT
NEET - 2019
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NEET 2025 - Target Batch
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NEET 2025 - Target Batch
False statement regarding PCl5 is:
| 1. | PCl5 molecule is non-reactive. |
| 2. | Three equatorial P-Cl bonds make an angle of 120° with each other. |
| 3. | Two axial P-Cl bonds make an angle of 180° with each other. |
| 4. | Axial P-Cl bonds are longer than equatorial P-Cl bonds. |
Subtopic: Group 15 - Preparation, Properties & Uses |
75%
From NCERT
NEET - 2019
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NEET 2025 - Target Batch
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