What is the rate constant for a reaction if the time taken by the first-order decomposition of \(\text{SO}_2\text{Cl}_2\) to decompose to 40% is 560 seconds?
[Given: log 2.5 = 0.3979]
1. \(2.726 \times 10^{-5} \mathrm{~min}^{-1}\) 2. \(2.276 \times 10^{-5} \mathrm{~min}^{-1}\)
3. \(2.216 \times 10^{-5} \mathrm{~min}^{-1}\) 4. None of the above
Subtopic:  First Order Reaction Kinetics |
Level 3: 35%-60%
NEET - 2024
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Effective collisions are known to possess:

A: Energy greater than the threshold energy.
B: Breaking of old bonds in the reactant.
C: Formation of a new bond in the product.
D: High activation energy.
E: Proper orientation.

Choose the correct answer from the options given below:
1. A, B, C, D only 2. A, B, C, E only
3. A, C, D, E only 4. B, C, D, E only
Subtopic:  Arrhenius Equation |
 72%
Level 2: 60%+
NEET - 2024
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Analyze the energy profile diagram and select the correct statement(s):
  
(P) Number of intermediates = 2
(Q) Number of transition states = 3
(R) Reaction is endothermic.

1. P & Q only.
2. P & R only.
3. Q & R only.
4. P, Q, R
Subtopic:  Arrhenius Equation |
 73%
Level 2: 60%+
Please attempt this question first.
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For the reaction, \(2 A+B \rightarrow 3 C+D\)

Which of the following is an incorrect expression for the rate of reaction?

1. \(-\frac{d[C]}{{3} d t }\) 2. \(-\frac{d[B]}{d t} \)
3. \(\frac{d[D]}{d t} \) 4. \(-\frac{d[A]}{2 d t}\)
Subtopic:  Definition, Rate Constant, Rate Law |
 90%
Level 1: 80%+
AIPMT - 2006
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The following reaction was carried out at 300 K.

2SO2(g)  +  O2(g) →  2SO3(g)

The rate of formation of SO3 is related to the rate of disappearance of O2  by the following expression:

1. -∆O2∆t=+12∆SO3∆t                           

2. -∆O2∆t=∆SO3∆t

3. -∆O2∆t=-12∆SO3∆t                           

4. None of the above.

Subtopic:  Definition, Rate Constant, Rate Law |
 89%
Level 1: 80%+
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For a general reaction A → B, the plot of the concentration of A vs. time is given in the figure.
 

The slope of the curve will be:

1. -k 2. -k/2
3. -k2 4. -k/3
Subtopic:  Definition, Rate Constant, Rate Law |
 90%
Level 1: 80%+
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The correct expression for the rate of reaction given below is:
\(5 \mathrm{Br}^{-}(\mathrm{aq})+\mathrm{BrO}_3^{-}(\mathrm{aq})+6 \mathrm{H}^{+}(\mathrm{aq}) \rightarrow 3 \mathrm{Br}_2(\mathrm{aq})+3 \mathrm{H}_2 \mathrm{O}(\mathrm{l})\)

1. \(\frac{\Delta\left[B r^{-}\right]}{\Delta t}=5 \frac{\Delta\left[H^{+}\right]}{\Delta t} \) 2. \(\frac{\Delta\left[\mathrm{Br}^{-}\right]}{\Delta t}=\frac{6}{5} \frac{\Delta\left[\mathrm{H}^{+}\right]}{\Delta t} \)
3. \(\frac{\Delta[\mathrm{Br^-}]}{\Delta t}=\frac{5}{6} \frac{\Delta\left[\mathrm{H}^{+}\right]}{\Delta t} \) 4. \(\frac{\Delta\left[\mathrm{Br}^{-}\right]}{\Delta t}=6 \frac{\Delta\left[\mathrm{H}^{+}\right]}{\Delta t}\)
Subtopic:  Definition, Rate Constant, Rate Law |
 89%
Level 1: 80%+
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A reaction is first-order with respect to A and second-order with respect to B. If the concentration of B is tripled while that of A remains constant, how will the rate of the reaction change?

1. Decrease 9 times 2. Increase 9 times
3. Increase 6 times 4. Decrease 6 times
Subtopic:  Definition, Rate Constant, Rate Law |
 90%
Level 1: 80%+
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Find the rates of formation of NO₂ and O₂, respectively, for the reaction:

N₂O₅(g) → 2NO₂(g) + ½O₂(g)

Given that the rate of disappearance of N₂O₅ is:

6.25 × 10⁻³ mol L⁻¹ s⁻¹.
 

1. 6.25 x 10-3 mol L-1s-1 and 6.25 x 10-3 mol L-1s-1

2. 1.25 x 10-2 mol L-1s-1 and 3.125 x 10-3 mol L-1s-1

3. 6.25 x 10-3 mol L-1s-1 and 3.125 x 10-3 mol L-1s-1

4. 1.25 x 10-2 mol L-1s-1 and 6.25 x 10-3 mol L-1s-1

Subtopic:  Definition, Rate Constant, Rate Law |
 87%
Level 1: 80%+
NEET - 2010
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During the formation of ammonia by Haber's process N2 + 3H2 → 2NH3, the rate of appearance of NH3 was measured as 2.5 x 10-4 mol L-1 s-1. The rate of disappearance of H2 will be: 

1. 2.5 x 10-4 mol L-1 s-1

2. 1.25 x 10-4 mol L-1 s-1

3. 3.75 x 10-4 mol L-1 s-1

4. 15.00 x 10-4 mol L-1 s-1

Subtopic:  Definition, Rate Constant, Rate Law |
 85%
Level 1: 80%+
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