| List-I (Quantitative Methods) |
List-II (Principle and reagents used) |
||
| A. | Thin Layer Chromatography | (i). | Partition Chromatography |
| B. | Yellow coloured | (ii). | Adsorption chromatography |
| C. | Paper chromatography | (iii). | Ammonia |
| D. | Kjeldahl method | (iv). | (NH4)3PO4.12MoO3 |
| A | B | C | D | |
| 1. | (iii) | (iv) | (ii) | (i) |
| 2. | (ii) | (iv) | (i) | (iii) |
| 3. | (ii) | (i) | (iv) | (iii) |
| 4. | (iii) | (iv) | (i) | (ii) |
| Assertion (A): | Kjeldahl method is not used for pyridine. |
| Reason (R): | Nitrogen of pyridine does not change to ammonium sulphate under these conditions. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
| 1. | Silica gel | 2. | Alumina |
| 3. | Benzene | 4. | Both (1) and (2) |
A mixture contains three volatile liquids: A, B, and C. It is observed that there is a large difference between the boiling point of liquid A and the boiling points of liquids B and C. However, the boiling points of liquids B and C are very close to each other. Which of the following sequence of techniques is most appropriate to completely separate all three liquids from the mixture?
| 1. | A is separated by simple distillation, then B & C by column chromatography |
| 2. | A is separated by simple distillation, then B & C by fractional distillation |
| 3. | A is separated by fractional distillation, then B & C by column chromatography |
| 4. | A is separated by fractional distillation, then B & C by simple distillation |
In an estimation of bromine by the Carius method, 1.6 g of an organic compound gave 1.88 g of AgBr. The mass percentage of bromine in the compound is:
[Atomic mass, Ag=108, Br = 80 g ]
1. 50 %
2. 55.5%
3. 60 %
4. 70 %