The strong reducing behaviour of H3PO2 is due to:

1. Presence of one -OH group and two P-H bonds.

2. High electron gain enthalpy of phosphorus.

3. High oxidation state of phosphorus.

4. Presence of two -OH groups and one P-H bond.

Subtopic:  Group 15 - Preparation, Properties & Uses |
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Nitrogen dioxide and sulphur dioxide have some properties in common. Which property is shown by one of these compounds, but not by the other?
1. Forms acid-rain

2. Is a reducing agent

3. Is soluble in water

4. Is used as a food-preservative

Subtopic:  Group 15 - Preparation, Properties & Uses |
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Which of the following compounds does not release oxygen when heated?

1. Zn(ClO3)2
2. K2Cr2O7
3. (NH4)2Cr2O7
4. KClO3

Subtopic:  Group 15 - Preparation, Properties & Uses |
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The incorrect statement regarding oxoacids of phosphorus is:

1. Orthophosphoric acid is used in the manufacture of triple superphosphate.
2. Hypophosphorous acid is a diprotic acid.
3. All oxoacids contain tetrahedral four coordinated phosphorus.
4. All oxoacids contain at least one P=O unit and one P-OH group.

Subtopic:  Group 15 - Preparation, Properties & Uses |
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The given sequence among the following arrangements that is not strictly according to the property indicated against it.  

1. H2O < H2S < H2Se < H2Te : \(\small{\text{increasing} \  p K_{a}\   \text{values}}\)
2. \(\small{\mathrm{N H_{3} <   P H_{3} <  A s H_{3} <  S b H_{3}} :   \text{increasing  acidic  character}}\)
3. \(\small{\mathrm{C O_{} <  S i O_{} <  S n O_{}   <  P b O_{2}} :  \text{increasing oxidising power}} \)
4. \(\small{\mathrm{H F  <  H C l   <  H B r  <  H I} :  \text{increasing acidic strength}} \)
Subtopic:  Group 17 - Preparation, Properties & Uses | Group 16 - Preparation, Properties & Uses | Group 15 - Preparation, Properties & Uses |
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Oxidation states of P in H4P2O5, H4P2O6, H4P2O7, are respectively:

1. +3, +5, +4 2. +5, +3, +4
3. +5, +4, +3 4. +3, +4, +5
Subtopic:  Group 15 - Preparation, Properties & Uses |
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Total number of  bridging oxygen atoms present in P4O10 are:

1. 4

2. 2

3. 5

4. 6

Subtopic:  Group 15 - Preparation, Properties & Uses |
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Match List-I (substances) with List-II (processes) employed in the manufacture of the substances and select the correct option.

List –I (Substances) List – II (Processes)
(a) Sulphuric acid (i) Haber's Process
(b) Steel (ii) Bessemer's Process
(c) Sodium carbonate (iii) Leblanc Process
(d) Ammonia  (iv) Contact Process

Options : (a) (b) (c) (d)
1. (i) (ii) (iii) (iv)
2. (iv) (iii) (ii) (i)
3. (iv) (ii) (iii) (i)
4. (i) (iv) (ii) (iii)
Subtopic:  Group 16 - Preparation, Properties & Uses | Group 15 - Preparation, Properties & Uses |
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The electronegativity difference between N and F is greater than that between N and H yet the dipole moment of NH3 (1.5 D) is larger than that of NF3 (0.2 D). This is because:

1. In NH3 as well as in NFthe atomic dipole and bond dipole are in the same direction
2. In NH3  the atomic dipole and bond dipole are in the same direction whereas in NF3 these are in opposite directions
3. In NH3 as well as in NFthe atomic dipole and bond dipole are in opposite directions
4. In NH3  the atomic dipole and the bond dipole is in opposite directions whereas in NF3 these are in the same directions

Subtopic:  Group 15 - Preparation, Properties & Uses |
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