The conductivity of centimolar solution of KCl at 25°C is 0.0210 ohm–1 cm–1 and the resistance of the cell containing the solution at 25°C is 60 ohm. The value of the cell constant is: 
1. 3.34 cm–1 2. 1.34 cm–1
3. 3.28 cm–1 4. 1.26 cm–1
Subtopic:  Conductance & Conductivity |
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The molar conductance of an electrolyte increases with dilution according to the equation: 
\(\Lambda_{\mathrm{m}}=\Lambda_{\mathrm{m}}^{\circ}-\mathrm{A} \sqrt{\mathrm{c}} \)
Consider the following four statements:
A: This equation applies to both strong and weak electrolytes.
B: The value of the constant A depends upon the nature of the solvent. 
C: The value of constant A is the same for both \(BaCl_2\) and \(MgSO_4\)
D: The value of constant A is the same for both \(BaCl_2\) and \(Mg(OH)_2\)
Which of the above statements are correct? 
1. (A) and (B) only  2. (A), (B), and (C) only 
3. (B) and (C) only  4. (B) and (D) only 
Subtopic:  Conductance & Conductivity |
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The molar conductance of a solution, given its conductivity (0.248 S m–1) and concentration (0.2 mol m–3) is:
1. 0.124 S cm2 mol–1
2. 1.24 S mmol–1
3. 124 S cm2 mol–1
4. 124 S m2 mol–1
Subtopic:  Conductance & Conductivity |
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\(\land^o_m\) for NaCl, HCl and \(\mathrm{CH_3COONa }\) are 126.4, 425.9, and 91.05 S cm2 mol–1 respectively. If the conductivity of 0.001028 mol L–1 acetic acid solution is \(4.95 \times 10^{-5} S ~cm^{-1} \), the degree of dissociation of the acetic acid solution is:

1. 0.01233 2. 1.00 
3. 0.1233  4. 1.233
Subtopic:  Conductance & Conductivity |
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Limiting molar conductivities, for the given solutions, are :

λm0(H2SO4)x cm2 mol-1

λm0(K2SO4)y cm2 mol-1

λm0(CH3COOK)z cm2 mol-1

From the data given above, it can be concluded that \(\lambda_m^0 \) in (\(S\ cm^2\ mol^{-1}\)) for CH3COOH will be :
1. \(\mathrm{x-y+2z}\)       
2. \(\mathrm{x+y+z}\)          
3. \(\mathrm{x-y+z}\)       
4. \(\mathrm{{(x-y) \over 2}+z}\)          

Subtopic:  Conductance & Conductivity |
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