The correct order of decreasing stability of the following carbocations is:

I \( \begin{aligned} &~~~~~~~~~~~~\oplus\\ & CH_3 - CH-CH_3 \end{aligned}\)
II \( \begin{aligned} &~~~~~~~~~~~~\oplus\\ & CH_3 - CH-OCH_3\end{aligned}\)
III \( \begin{aligned} & ~~~~~~~~~~~~\oplus\\ &CH_3 - CH-CH_2- OCH_3\end{aligned}\)
 
1. II > I > III 2. I > II > III
3. II < I < III 4. I < II < III
Subtopic:  Electron Displacement Effects |
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Which of the following carbon marked with asterisk is expected to have greatest positive charge?

1. *CH3-CH2-Cl 2. *CH3-CH2-Mg+Cl-
3. *CH3-CH2-Br 4. *CH3-CH2-CH3
Subtopic:  Electron Displacement Effects |
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Which carboxylate ion among the following is the most stable?

1. 2.
3. 4.

Subtopic:  Electron Displacement Effects |
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Match the ions given in Column I with their nature-given in Column II.

Column I

Column II

A. 

1. Stable due to resonance

B.  

2. Destabilised due to inductive effect

C. 

3. Stabilised by hyperconjugation.

D.  

4. A secondary carbocation

Codes:

Options:  A   B   C   D 
1.  1,2  2 2  3,4 
2. 1 2,4   3  4
3.  1  4  3  2
4.  4  1  3  2

Subtopic:  Electron Displacement Effects | Reaction Intermediates ; Preparation & Properties |
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Arrange the following carbanions in order of their decreasing stability:

A. \(\mathrm{H}_3 \mathrm{C}-\mathrm{C} \equiv \mathrm{C}^{-}\)
B. \(\mathrm{H}-\mathrm{C} \equiv \mathrm{C}^{-}\)
C. \(\mathrm{H}_3 \mathrm{C}-\mathrm{{C}H_2^-}\)

 
1. A > B > C 2. B > A > C
3. C > B > A 4. C > A > B
Subtopic:  Electron Displacement Effects |
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Hyperconjugation involves delocalization of -

a. Electrons of carbon-hydrogen σ bond of an alkyl group directly attached to an atom of unsaturated system.
b. Electrons of carbon-hydrogen σ bond of alkyl group directly attached to the positively charged carbon atom.
c. π-electrons of carbon-carbon bond
d. Lone pair of electrons.

Choose the correct option :

1. (a, b)

2. (b, c)

3. (c, d)

4. (a, c)

Subtopic:  Electron Displacement Effects |
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