Identify the incorrect statement:
1. The relative stability of group 13 elements in +1 oxidation state varies as : Al < Ga < In < Tl.
2. Boron trioxide is acidic, aluminium and gallium trioxides are amphoteric while indium and thallium trioxides are basic.
3. The hybridisation of Al in \(\left[\mathrm{Al}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}\) is \(\text{d}^2\text{ sp}^3.\)
4. Two isotopes of Boron, namely \(^{10}\!\mathrm{~B}(19 \%)\) and \(^{11}\! \mathrm{~B}(81 \%)\) are known.
Subtopic:  Boron Family- Preparations, Properties & Uses |
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Select the element (M) whose trihalides cannot be hydrolysed to form [M(H2O)6]3+.
1. Ga 2. In 
3. Al 4. B
Subtopic:  Boron Family- Preparations, Properties & Uses |
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The \(E^{\ominus}\) values for 
\(\begin{aligned} & \mathrm{Al}^+ / \mathrm{Al}=+0.55 \mathrm{~V} \text { and } \mathrm{Tl}^{+} / \mathrm{Tl}=-0.34 \mathrm{~V} \\ & \mathrm{Al}^{3+} / \mathrm{Al}=-1.66 \mathrm{~V} \text { and } \mathrm{Tl}^{3+} / \mathrm{Tl}=+1.26 \mathrm{~V} \end{aligned} \)
The incorrect statement among the following is:

1. Al is more electropositive than TI 
2. Tl3+ is a good reducing agent than Tl1+
3. Al+ is unstable in solution. 
4. Tl can be easily oxidized to Tl+ as compared to Tl3+
Subtopic:  Boron Family- Preparations, Properties & Uses |
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Which of the following is the correct statement?
1. Ga+ is more stable than ln+.
2. Al+ is more stable than ln+.
3. Ga+ is more stable than Al+.
4. Al+ is more stable than Ga+.

Subtopic:  Boron Family- Preparations, Properties & Uses |
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Aluminium chloride in acidified aqueous solution forms a complex 'A'.
The formula of A and hybridisation state of Al in 'A' is respectively:

1. [Al(H2O)6]3+, sp3d2

2. [Al(H2O)4]3+, sp3

3. [Al(H2O)4]3+, dsp2

4. [Al(H2O)]3+, d2sp3

Subtopic:  Boron Family- Preparations, Properties & Uses |
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