For the reaction \(2 \mathrm{~A} \rightleftharpoons \mathrm{B}+\mathrm{C}, \mathrm{K}_{\mathrm{c}}=4 \times 10^{-3}\) . At a given time, the composition of reaction mixture is : \([\mathrm{A}]=[\mathrm{B}]=[\mathrm{G}]=2 \times 10^{-3} \mathrm{M} \text {. }\)
 Then, which of the following is correct?
1. Reaction has a tendency to go in forward direction.
2. Reaction has a tendency to go in backward direction.
3. Reaction has gone to completion in forward direction.
4. Reaction is at equilibrium.
Subtopic:  Introduction To Equilibrium |
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In which of the following equilibria, \(\text{K}_\text{p}\) and \(\text{K}_\text{c}\) are NOT equal?

1. \(\mathrm{H}_{2(\mathrm{~g})}+\mathrm{I}_{2(\mathrm{~g})} \rightleftharpoons 2 \mathrm{HI}_{(\mathrm{g})}\)
2. \(\mathrm{CO}_{(\mathrm{g})}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{g})} \rightleftharpoons \mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_{2(\mathrm{~g})}\)
3. \(2 \mathrm{BrCl}_{(\mathrm{g})} \rightleftharpoons \mathrm{Br}_{2(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})}\)
4. \(\mathrm{PCl}_{5(\mathrm{~g})} \rightleftharpoons \mathrm{PCl}_{3(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})}\)
Subtopic:  Kp, Kc & Factors Affecting them |
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Consider the following reaction in a sealed vessel at equilibrium with concentrations of 
\(\text{N}_2=3.0 \times 10^{-3} \text{M}, \text{O}_2=4.2 \times 10^{-3} \text{M}\) and 
\(\text{NO}=2.8 \times 10^{-3}\)
\(2 \text{NO}_{(\text{g})} \rightleftharpoons \text{N}_{2(\text{g})} +\text{O}_{2\text{(g)}}\)
If 0.1 mol L-1 of NO(g) is taken in a closed vessel, what will be degree of dissociation (\(\alpha\)) of NO(g) at equilibrium?

1. 0.0889
2. 0.8889
3. 0.717
4. 0.00889
Subtopic:  Ionisation Constant of Acid, Base & Salt |
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Consider the reaction in equilibrium 
\(\mathrm{PCl}_5=\mathrm{PCl}_3+\mathrm{Cl}_2\)
at \(500 \mathrm{~K} .\) The concentration of \(\mathrm{PCl}_5=1.40~ \mathrm{M} \text {, }\) concentration of \(\mathrm{Cl}_2=1.60~ \mathrm{M} \text {, }\) concentration of \(\mathrm{PCl}_3=1.60 \mathrm{M}\). Calculate \(K_c\):

1. 2.00
2. 2.6
3. 1.83
4. 3.4
Subtopic:  Kp, Kc & Factors Affecting them |
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For the equilibrium
\(\mathrm{2NOCl_\text{(g)}\rightleftharpoons2NO_{\text{(g)}}+Cl_{2{\text{(g)}}}}\)
the value of the equilibrium constant is \(3.0\times10^{-6} \) at \(1000~K.\) Find \(K_p\) for the reaction at this temperature (Given \(R:8.314~\text{J K}^{-1}\text{mol}^{-1}\)):

1. \(1.493\)
2. \(2.494\times10^{-2}\)
3. \(3.0\times10^{-6}\)
4. \(2.494\times10^{-4}\)
Subtopic:  Kp, Kc & Factors Affecting them |
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At a given temperature and pressure, the equilibrium constant value for the equilibria are given below:
\(3A_2+B_2\rightleftharpoons 2A_3B, K_1\\ A_3B \rightleftharpoons \frac 3{2}A_2+\frac 1{2}B_2, K_2 \)
The relation between \(K_1\) and \(K_2\) is: 
1. \(K^2_1=2K_2\)
2. \(K_2= \frac { K_1 }{2}\)
3. \(K_1=\frac 1{\sqrt K_2}\)
4. \(K_2=\frac 1{\sqrt K_1}\)
Subtopic:  Introduction To Equilibrium |
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For the reaction in equilibrium 
\(\mathrm{N_2(g) +3H_2(g) \rightleftharpoons 2NH_3(g), \Delta H=-Q}\)
Reaction is favoured in forward direction by:
1. Use of catalyst 
2. Decreasing concentration of \(\mathrm{N_2}\)
3. Low pressure, high temperature and high concentration of ammonia
4. High pressure, low temperature and higher concentration of \(\mathrm{H_2}\)
Subtopic:  Le Chatelier's principle |
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The ratio of solubility of \(\mathrm{AgCl}\) in \(0.1~ \mathrm{M} ~\mathrm{KCl}\) solution to the solubility of \( \mathrm{Ag} \mathrm{Cl}\) in water is:
(Given : Solubility product of \(\mathrm{AgCl}=10^{-10}\) )
1. \(10^{-4}\)
2. \(10^{-6}\)
3. \(10^{-9}\)
4. \(10^{-5}\)
Subtopic:  Solubility Product |
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Amongst the given option which of the following molecules/ion acts as a Lewis acid? 
1. \(\text{OH}^- \)
2. \(\text{NH}_3 \)
3. \(\text H_2 \text O \)
4. \(\text{BF}_3 \)
Subtopic:  Acids & Bases - Definitions & Classification |
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The equilibrium concentration of the species in the reaction \(A+B \rightleftharpoons C+D\) are 2, 3, 10 and 6 mol L–1, respectively at 300 K. \(\Delta G^o\) for the reaction is: (R = 2 cal/mol K) 
1. –13.73 cal  2. 1372.60 cal 
3. –137.26 cal  4. –1381.80 cal
Subtopic:  Introduction To Equilibrium |
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