In which of the following equilibria, \(\text{K}_\text{p}\) and \(\text{K}_\text{c}\) are NOT equal?

1. \(\mathrm{H}_{2(\mathrm{~g})}+\mathrm{I}_{2(\mathrm{~g})} \rightleftharpoons 2 \mathrm{HI}_{(\mathrm{g})}\)
2. \(\mathrm{CO}_{(\mathrm{g})}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{g})} \rightleftharpoons \mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_{2(\mathrm{~g})}\)
3. \(2 \mathrm{BrCl}_{(\mathrm{g})} \rightleftharpoons \mathrm{Br}_{2(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})}\)
4. \(\mathrm{PCl}_{5(\mathrm{~g})} \rightleftharpoons \mathrm{PCl}_{3(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})}\)
Subtopic:  Kp, Kc & Factors Affecting them |
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Consider the reaction in equilibrium 
\(\mathrm{PCl}_5=\mathrm{PCl}_3+\mathrm{Cl}_2\)
at \(500 \mathrm{~K} .\) The concentration of \(\mathrm{PCl}_5=1.40~ \mathrm{M} \text {, }\) concentration of \(\mathrm{Cl}_2=1.60~ \mathrm{M} \text {, }\) concentration of \(\mathrm{PCl}_3=1.60 \mathrm{M}\). Calculate \(K_c\):

1. 2.00
2. 2.6
3. 1.83
4. 3.4
Subtopic:  Kp, Kc & Factors Affecting them |
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For the equilibrium
\(\mathrm{2NOCl_\text{(g)}\rightleftharpoons2NO_{\text{(g)}}+Cl_{2{\text{(g)}}}}\)
the value of the equilibrium constant is \(3.0\times10^{-6} \) at \(1000~K.\) Find \(K_p\) for the reaction at this temperature (Given \(R:8.314~\text{J K}^{-1}\text{mol}^{-1}\)):

1. \(1.493\)
2. \(2.494\times10^{-2}\)
3. \(3.0\times10^{-6}\)
4. \(2.494\times10^{-4}\)
Subtopic:  Kp, Kc & Factors Affecting them |
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The equilibrium of three reactions with their respective equilibrium constants are given below,

\( \begin{array}{lc} \mathrm{N}_2+3 \mathrm{H}_2 \rightleftharpoons 2 \mathrm{NH}_3 & \mathrm{~K}_1 \\ \mathrm{~N}_2+\mathrm{O}_2 \rightleftharpoons 2 \mathrm{NO} & \mathrm{K}_2 \\ \mathrm{H}_2+\frac{1}{2} \mathrm{O}_2 \rightleftharpoons \mathrm{H}_2 \mathrm{O} & \mathrm{K}_3 \end{array} \)

The equilibrium constant (K) of the following reaction will be : 
2NH3+52O2 K 2NO+3H2O

1. \( \frac{K_{2}K_{3}^{3}}{K_{1}}\)
2. \( \frac{K_{2}K_{3}}{K_{1}}\)
3. \( \frac{K_{2}^{3}K_{3}}{K_{1}}\)
4. \( \frac{K_{3}^{3}K_{1}}{K_{2}}\)

Subtopic:  Kp, Kc & Factors Affecting them |
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A 20-litre container at 400 K contains CO2 (g) at pressure 0.4 atm and an excess of SrO (neglecting the volume of solid SrO). The volume of the container is now decreased by moving the movable piston fitted in the container.
The maximum volume of the container, when the pressure of CO2 attains its maximum value will be:
(Given that: SrCO3(s) ⇋ SrO(s) + CO2(g) , Kp = 1.6 atm) 

1. 10 litre 2. 2 litre
3. 4 litre 4. 5 litre
Subtopic:  Kp, Kc & Factors Affecting them |
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If the equilibrium constant for N2(g) + O2 (g) ⇄ 2NO(g) is K, the equilibrium constant for \(\frac{1}{2}\)N2(g) + \(\frac{1}{2}\)O2(g) ⇄ NO(g) will be?

1. K12

2. 12K

3. K

4. K2

Subtopic:  Kp, Kc & Factors Affecting them |
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The value of the equilibrium constant for a particular reaction is 1.6 × 1012. When the system is in equilibrium, it will include:
1. All reactants
2. Mostly reactants
3. Mostly products
4. Similar amounts of reactants and products

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Given that the equilibrium constant for the reaction 

2SO2(g) + O2(g)  2SO3(g) 

has a value of 278 at a particular temperature, the value of the equilibrium constant for the following reaction at the same temperature will be:

SO3(g)   SO2(g) + 1/2 O2(g) 

1.  3.6 × 10-3 

2.  6.0 × 10-2 

3.  1.3 × 10-5 

4.  1.8 × 10-3 

Subtopic:  Kp, Kc & Factors Affecting them |
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Consider the following reaction:
A2(g) + B2(g)  ⇋ 2AB(g)  
At equilibrium, the concentrations of  A2 = 3.0×10–3 M;  B2 = 4.2×10–3 M and AB = 2.8×10–3M.
The value \(K_C\) for the above-given reaction in a sealed container at 527°C is:

1. 3.9  2. 0.6 
3. 4.5 4. 2.0 
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For the reaction N2(g) + O2(g)2NO(g) the equilibrium constant is K1. The equilibrium constant is K2 for the reaction  2NO(g) + O2(g) 2NO2(g) 
The value of K for the reaction given below will be:
NO2(g)12N2(g) +O2(g) 

1.  14 4 K1 K2

2.  1K1K21/2

3.  1K1K2

4.  12K1K2

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