The heat of combustion of carbon to CO2 is –393.5 KJ/mol. The heat released upon the formation of 35.2 g of CO2 from carbon and oxygen gas is:
1. –315 KJ
2. +315 KJ
3. –630 KJ
4. +630 KJ

Subtopic:  Thermochemistry |
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Consider the following reactions: 

(i) H+(aq) + OH-(aq) → H2O(l)
ΔH = -x1 kJmol-1
(ii) H2(g) + 1/2O2(g) → H2O(l)
ΔH = -x2 kJmol-1
(iii) CO2(g) + H2(g) → CO (g) + H2O(l)
ΔH = -x3 kJmol-1
(iv) C2H2(g) + 5/2O2(g) →  2CO+ H2O(l)
ΔH = -x4 kJmol-1


Enthalpy of formation of H2O(l) is :

1. -x3 kJ mol-1

2. -x4 kJ mol-1

3. -x1 kJ mol-1

4. -x2 kJ mol-1

Subtopic:  Thermochemistry |
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Assertion (A): All combustion reactions are exothermic.
Reason (R): For an exothermic reaction, enthalpies of products are greater than enthalpies of reactants \({(\Sigma v_p\Delta_fH(P)> \Sigma v_R\Delta_fH(R))}\).
 
1.  Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.


 
Subtopic:  Thermochemistry |
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\(\Delta_fH^\circ\) is non-zero for which of the following species?
1. \(S_\text{monoclinic}\)
2.  \(C_\text{graphite}\)
3. H2(g)
4.  \(O_2(g)\)
Subtopic:  Thermochemistry |
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Given, the following reaction:

N2H4(g)          N2H2(g)+H2(g);
Given:  ∆ H= 109 kJ/mol

B.E. of (N-N) = 163 kJ/mol

B.E. of (N-H) = 391 kJ/mol

B.E. of (H-H) = 436 kJ/mol

Calculate the bond enthalpy of N = N.

1. 182 kJ/mol

2. 400 kJ/mol

3. 300 kJ/mol

4. 218 kJ/mol

Subtopic:  Thermochemistry |
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