Consider the following reaction:
\(\mathrm{2H_2(g) + O_2(g) \rightarrow 2H_2O(g) \Delta_rH^\circ = -483.64 kJ. }\)
What is the enthalpy change for the decomposition of one mole of water?
1. 120.9 kJ 2. 241.82 kJ
3. 18 kJ 4. 100 kJ
Subtopic:  Thermochemistry |
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At standard conditions, if the change in the enthalpy for the following reaction is –109 kJ mol
H2(g)+Br2(g)2HBr(g) and the bond energy of H2 and Br2 is 435 kJ mol–1 and 192 kJ mol–1 respectively, what is the bond energy (in kJ mol–1) of HBr?

1. 368 2. 736
3. 518 4. 259
Subtopic:  Thermochemistry |
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The bond dissociation energies of X2 , Y2 and XY are in the ratio of 1 : 0.5 : 1. ∆H for the formation of XY is –200 kJ mol–1. The bond dissociation energy of X2 will be

1. 200 kJ mol–1
2. 100 kJ mol–1
3. 800 kJ mol–1
4. 400 kJ mol–1

Subtopic:  Thermochemistry |
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The heat of combustion of carbon to CO2 is –393.5 KJ/mol. The heat released upon the formation of 35.2 g of CO2 from carbon and oxygen gas is:
1. –315 KJ
2. +315 KJ
3. –630 KJ
4. +630 KJ

Subtopic:  Thermochemistry |
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The enthalpy of fusion of water is 1.435 kcal/mol. The molar entropy change for the melting of ice at 0 oC is:

1. 10.52 cal/(mol K)

2. 21.04 cal/(mol K)

3. 5.260 cal/(mol K)

4. 0.526 cal/(mol K)

Subtopic:  Thermochemistry |
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From the following bond energies:
H—H bond energy: 431.37 kJ mol-1 
C=C bond energy: 606.10 kJ mol-1 
C—C bond energy: 336.49 kJ mol-1 
C—H bond energy: 410.50 kJ mol-1 
Enthalpy for the reaction, 

will be:

1. 1523.6 kJ mol-1 2. -243.6 kJ mol-1
3. -120.0 kJ mol-1 4. 553.0 kJ mol-1
Subtopic:  Thermochemistry |
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Bond dissociation enthalpy of H2, Cl2, and HCl are 434, 242, and 431 kJ mol1 respectively. Enthalpy of formation of HCl is:

1. 93 kJ mol-1
2. - 245 kJ mol-1
3. -93 kJ mol-1
4. 245 kJ mol-1

Subtopic:  Thermochemistry |
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Consider the following reactions: 

(i) H+(aq) + OH-(aq) → H2O(l)
ΔH = -x1 kJmol-1
(ii) H2(g) + 1/2O2(g) → H2O(l)
ΔH = -x2 kJmol-1
(iii) CO2(g) + H2(g) → CO (g) + H2O(l)
ΔH = -x3 kJmol-1
(iv) C2H2(g) + 5/2O2(g) →  2CO+ H2O(l)
ΔH = -x4 kJmol-1


Enthalpy of formation of H2O(l) is :

1. -x3 kJ mol-1

2. -x4 kJ mol-1

3. -x1 kJ mol-1

4. -x2 kJ mol-1

Subtopic:  Thermochemistry |
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The bond energy of H—H and Cl-Cl is 430 kJ mol-1 and 240 kJ mol-1 respectively
and ΔHf for HCl is -90 kJ mol-1. The bond enthalpy of HCl is:

1. 290 kJ mol-1

2. 380 kJ mol-1

3. 425 kJ mol-1

4. 245 kJ mol-1

Subtopic:  Thermochemistry |
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The enthalpy of combustion of H2, cyclohexene (C6H10) and cyclohexane (C6H12) are -241, -3800 and -3920 kJ per mol respectively. Heat of hydrogenation of cyclohexene is:

1. -121 kJ per mol

2. +121 kJ per mol

3. +242 kJ per mol

4. -242 kJ per mol

Subtopic:  Thermochemistry |
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