Intramolecular hydrogen bonding is present in:
1.  2. 
3.  HF 4. 
Subtopic:  van der Waal Force & Hydrogen Bonding |
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Match List I with List II.
List I
(Compound )
List II
(Shape/geometry)
A. NH3 I. Trigonal Pyramidal
B. BrF5 II. Square planar
C. XeF4 III. Octahedral
D. SF6 IV. Square Pyramidal
Choose the correct answer from the option given below:

1. A-II, B-IV, C-III, D-I
2. A-III, B-IV, C-I, D-II
3. A-II, B-III, C-IV, D-I
4. A-I, B-IV, C-II, D-III
Subtopic:  V.S.E.P.R & V.B.T |
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Identify the correct answer:

1. BF3 has non-zero dipole moment.
2. Dipole moment of NF3 is greater than that of NH3.
3. Three canonical forms can be drawn for \(\text{CO}_3^{2-}\) ion.
4. Three resonance structures can be drawn for ozone.
Subtopic:  Polarity | Resonance & Nature of Compounds |
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Which one of the following molecules is paramagnetic?

1. \(\mathrm{H}_2\)
2. \(\mathrm{Li}_2\)
3. \(\mathrm{C_2}\)
4. \(\mathrm{O}_2\)
Subtopic:  M.O.T |
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Arrange the following hydrides in the order of decreasing bond angle:
A. \( \mathrm{SbH}_3 \)
B. \( \mathrm{AsH}_3 \)
C. \(\mathrm{PH}_3 \)
D. \( \mathrm{NH}_3\)
Choose the correct answer from the options given below:
1. B > A > D > C 2. B > A > C > D 
3. D > C > B > A  4. A > C > B > D
Subtopic:  V.S.E.P.R & V.B.T |
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The correct shape and hybridisation of \(\text{BrF}_5\) is:

1. Square pyramidal and \(\text{sp}^3\text{d}^2\)
2. Square pyramidal and \(\text{d}^2\text{sp}^3\)
3. Trigonal bipyramidal and \(\text{sp}^3\text{d}^2\)
4. Trigonal bipyramidal and \(\text{d}^2\text{sp}^3\)
Subtopic:  V.S.E.P.R & V.B.T |
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Which pair of the following compounds has one lone pair of electrons on the central atom?

1. \(\mathrm{SF}_4, \mathrm{BrF}_5\)
2. \(\mathrm{SF}_4, \mathrm{ClF}_3\)
3. \(\mathrm{ClF}_3, \mathrm{XeF}_4\)
4. \(\mathrm{XeF}_4, \mathrm{BrF}_5\)
Subtopic:  V.S.E.P.R & V.B.T |
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Which of the following molecules has "NON ZERO" dipole moment value? 
1. \(\mathrm{CCl_4}\) 2. \(\mathrm{HI}\)
3. \(\mathrm{CO_2}\) 4.  \(\mathrm{BF}_3\)
Subtopic:  Polarity |
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Match column I(Molecule) with Column II(Bond enthalpy) and mark the correct option.
 
Column-I 
(Molecule) 
Column-II
(Bond enthalpy) 
\(\left(k J \mathrm{~mol}^{-1}\right)\)
A.  HCl I.  435.8
B. \(\mathrm{N_2}\) II.  498
C.  \(\mathrm{H_2}\) III.  946.0
D.  \(\mathrm{O_2}\) IV.  431.0

1. A-III, B-IV, C-I, D-II
2. A-IV, B-I, C-III, D-II
3. A-IV, B-III, C-II, D-I 
4. A-IV, B-III, C-I, D-II
Subtopic:  Types of Chemical Bond |
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The correct order of energies of molecular orbitals of N2 molecule is:
 
1. \( \sigma \text { 1s }<\sigma^* \text { 1s }<\sigma 2 s<\)
\(\sigma^* 2 s<\left(\pi 2 p_x=\pi 2 p_y\right)<\)
\(\left(\pi^* 2 p_x=\pi^* 2 p_y\right)<\sigma 2 p_z<\sigma^* 2 p_z\)
2. \( \sigma \text { 1s }<\sigma^* \text { 1s }<\sigma 2 s<\sigma^* 2 s<\)
\(\left(\pi 2 p_x=\pi 2 p_y\right)< \)
\(\sigma 2 p_z<\left(\pi^* 2 p_x=\pi^* 2 p_y\right)<\sigma^* 2 p_z \)
3. \( \sigma \text { 1s }<\sigma^* \text { 1s }<\sigma 2 s<\sigma^* 2 s<\sigma 2 p_z<\)
\( \left(\pi 2 p_x=\pi 2 p_y\right)<\)
\(\left(\pi^* 2 p_x=\pi^* 2 p_y\right)<\sigma^* 2 p_z \)
4. \( \sigma \text { 1s }<\sigma^* \text { 1s }\)
\(<\sigma 2 s<\sigma^* 2 s<\sigma 2 p_z< \)
\( \sigma^* 2 p_z<\left(\pi 2 p_x=\pi 2 p_y\right)<\)
\(\left(\pi^* 2 p_x=\pi^* 2 p_y\right) \)
Subtopic:  M.O.T |
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