Which one of the following species has a plane triangular shape?

Isostructural pair among the following is:

1. ${\mathrm{BCl}}_3$ $\mathrm{and}$ ${\mathrm{BrCl}}_3$

2. ${\mathrm{NH}}_3$ $\mathrm{and}$ ${\mathrm{NO}}_3^{-}$

3. ${\mathrm{NF}}_3$ $\mathrm{and}$ ${\mathrm{BF}}_3$

4. ${\mathrm{BF}}_4^{-}$ $\mathrm{and}$ ${\mathrm{NH}}_4^{+}$

Which of the following species contains three bond pairs and one lone pair around the central atom?

1. \(\text H_{2} \text O\)

2. \(\text{BF}_{3}\)

3. \(\text{NH}^-_2\)

4. \(\text{PCl}_{3}\)

Which of the two ions from the list given below have the geometry that is explained by the same hybridisation of orbitals, ${\mathrm{NO}}_2^{-},{\mathrm{NO}}_3^{-},{\mathrm{NH}}_2^{-},{\mathrm{NH}}_4^{-},{\mathrm{SCN}}^{-}$ ?

1.  ${\mathrm{NH}}_4^{-}$ $\mathrm{and}$ ${\mathrm{NO}}_3^{-}$

2.  ${\mathrm{SCN}}_{}^{-}$ $\mathrm{and}$ ${\mathrm{NH}}_2^{-}$

3.  ${\mathrm{NO}}_2^{-}$ $\mathrm{and}$ ${\mathrm{NH}}_2^{-}$

4.  ${\mathrm{NO}}_2^{-}$ $\mathrm{and}$ ${\mathrm{NO}}_3^{-}$

In which of the following pairs of molecules/ions, the central atoms have sp² hybridization?

1. $N{O}_2^{-}$ $and$ $N{H}_3$

2. $B{F}_3$ $and$ $N{O}_2^{-}$

3. $N{H}_2^{-}and$ $H_{2}O$

4. $B{F}_3$ $and$ $N{H}_2^{-}$

The correct order of increasing bond angles in the following species is:

1. \(C l_{2} O < C l O_{2} < C l O_{2}^{-}\)

2. \(C l O_{2} < C l_{2} O < C l O_{2}^{-}\)

3. \(C l_{2} O < C l O_{2}^{-} < C l O_{2}\)

4. \(C l O_{2}^{-} < C l_{2} O < C l O_{2}\)

In which one of the following species the central atom has the type of hybridization which is not the same as that present in the other three?

1. ${\mathrm{SF}}_4$

2. ${\mathrm{I}}_3^{-}$

3. ${\mathrm{SbCl}}_5^{2-}$

4. ${\mathrm{PCl}}_5$

Some of the properties of the two species, $N{O}_3^{-}$ $and$ $H_3{O}^{+}$  are described below. Which one of them is correct?