Given below are two statements: 
Assertion (A): Generally, ionisation enthalpy increases from left to right in a period.
Reason (R): When successive electrons are added to the orbitals in the same principal quantum level, the shielding effect of inner core of electrons does not increase very much to compensate for the increased attraction of the electron to the nucleus.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.

Subtopic:  Ionization Energy (IE) | Electron Affinity (EA) |
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The formation of the oxide ion O2– (g), from the oxygen atom requires first an exothermic and then an endothermic step as shown below, 
Og+e-O-; fH0=141 kJ mol-1
O-g+e-O2-g; fH0=+780 kJ mol-1

Thus, the process of formation of O2– in the gas phase is unfavorable even though O2– is isoelectronic with neon. It is due to the fact that:

1. Electron repulsion outweighs the stability gained by achieving noble gas configuration.
2. O ion has a comparatively smaller size than the oxygen atom.
3. Oxygen is more electronegative.
4. Addition of electrons in oxygen results in a large size of the ion.
Subtopic:  Electron Affinity (EA) |
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Electronic configuration of some elements is given in Column I and their electron gain enthalpies are given in Column II. Match the electronic configuration with electron gain enthalpy.

Column I

(Electron configuration)

Column II

(Electron gain enthalpy/kJ mol–1)

A. 

1s22s22p6

1.

–53

B. 

1s22s22p63s1

2.

–328

C. 

1s22s22p5

3.

–141

D. 

1s22s22p4

4.

+48

Codes:

Options:  A   B   C   D 
1.  4 1 2 3
2. 1 2 3 5
3. 1 4 3 2
4. 4 1 3 2

Subtopic:  Electron Affinity (EA) |
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The correct order of least negative to most negative electron gain enthalpy for C, Ca, Al, F and O is: 

1. Al < Ca < O < C < F
2. Al < O < C < Ca < F
3. C < F < O < Al < Ca
4. Ca < Al < C < O < F
Subtopic:  Electron Affinity (EA) |
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