Which of the following facts about the complex [Cr(NH3)6]Cl3 is wrong?
1. | The complex is an outer orbital complex. |
2. | The complex gives a white precipitate with a silver nitrate solution. |
3. | The complex involves d2sp3 hybridization and is octahedral in shape. |
4. | The complex is paramagnetic. |
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The correct order of the stoichiometries of AgCl formed when AgNO3 in excess is treated with the complexes: CoCl3.6NH3, CoCl3 .5NH3, CoCl3.4NH3 respectively is:
1. 3AgCl, 1AgCl, 2AgCl
2. 3AgCl, 2AgCl, 1AgCl
3. 2AgCl, 3AgCl, 1AgCl
4. 1AgCl, 3AgCl, 2AgCl
The type of isomerism shown by the complex is:
1. | Geometrical isomerism | 2. | Coordination isomerism |
3. | Ionization isomerism | 4. | Linkage isomerism |
The geometry and magnetic behaviour of the complex [Ni(CO)4] respectively are:
1. Square planar and diamagnetic.
2. Tetrahedral and diamagnetic.
3. Square planar and paramagnetic.
4. Tetrahedral and paramagnetic.
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Which of the following has the longest C —O bond length? (Free C—O bond length in CO is 1.128 )
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Number of possible isomers for the complex [Co(en)2Cl2]Cl will be:
(en=ethylenediamine)
1. | 2 | 2. | 1 |
3. | 3 | 4. | 4 |
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The hybridization involved in complex is : (Atomic number of Ni=28)
1.
2.
3.
4.
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The IUPAC name for complex ion, [Fe(CN)6]3- is:
1. | Hexacyanoiron(III) ion | 2. | Hexacyanitoferrate(III) ion |
3. | Tricynoferrate(III) ion | 4. | Hexacyanidoferrate(III) ion |
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Among the following complexes the one which shows zero crystal field stabilization energy (CFSE) is
1.
2.
3.
4.