In Fe (CO)5, the Fe-C bond possesses

1. ionic character

2. σ-character only

3. π-character only

4. both σ and π character

Subtopic:  Organometallic Complexes & their Uses |
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Which of the following pairs represents linkage isomers?

1. [Co(NH3)5NO3]SO4 and [Co(NH3)5SO4]NO3

2. [PtCl2)(NH3)4]Br2 and [PtBr2(NH3)4]Cl2

3. [Cu(NH3)4[PtCl4] and [Pt(NH3)4][CuCl4]

4. [Pd(PPh3)2(NCS)2 and [Pt(PPh3)2(SCN)2]

Subtopic:  Isomerism in Coordination Compounds |
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A solution containing 2.675 g of CoCl3.6NH3 (molar mass=267.5 g mol-1) is passed through a cation exhanger. The chloride ions obtained in solution were treated with excess of AgNO3 to give 4.78 g of AgCl (molar mass = 143.5 g mol-1). The formula of the complex is
(At. mass of Ag = 108 u)

1. [CoCl(NH3)5]Cl2

2. [Co(NH3)6Cl3

3. [CoCl2(NH3)4]Cl

4. [CoCl3(NH3)3]

Subtopic:  Introduction, Classification and Nomenclature | Werner’s Theory |
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Which of the following facts about the complex [Cr(NH3)6]Cl3 is wrong?

1.  The complex is an outer orbital complex.
2.  The complex gives a white precipitate with a silver nitrate solution.
3.  The complex involves d2sp3 hybridization and is octahedral in shape.
4.  The complex is paramagnetic.

Subtopic:  VBT, CFT & their Limitations |
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The correct order of the stoichiometries of AgCl formed when AgNO3 in excess is treated with the complexes: CoCl3.6NH3, CoCl3 .5NH3, CoCl3.4NH3 respectively is:

1. 3AgCl, 1AgCl, 2AgCl

2. 3AgCl, 2AgCl, 1AgCl

3. 2AgCl, 3AgCl, 1AgCl

4. 1AgCl, 3AgCl, 2AgCl

Subtopic:  Werner’s Theory |
 90%
From NCERT
NEET - 2017
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The type of isomerism shown by the complex  CoCl2en2 is:

1. Geometrical isomerism 2. Coordination isomerism
3. Ionization isomerism 4. Linkage isomerism
Subtopic:  Isomerism in Coordination Compounds |
 83%
From NCERT
NEET - 2018
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The geometry and magnetic behaviour of the complex [Ni(CO)4] respectively are:

1. Square planar and diamagnetic.

2. Tetrahedral and diamagnetic.

3. Square planar and paramagnetic.

4. Tetrahedral and paramagnetic.

Subtopic:  VBT, CFT & their Limitations |
 63%
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NEET - 2018

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Which of the following has the longest C ­—O bond length? (Free C—O bond length in CO is 1.128 )

1. [Co(CO)4]-
2. [Fe(CO)4]2-
3. Mn(CO)6]+
4. Ni(CO)4
Subtopic:  VBT, CFT & their Limitations |
 87%
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NEET - 2016

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Number of possible isomers for the complex [Co(en)2Cl2]Cl will be:
(en=ethylenediamine) 

1. 2 2. 1
3. 3 4. 4
Subtopic:  Isomerism in Coordination Compounds |
 63%
From NCERT
NEET - 2015

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