Reactions among the following that occur during calcination are:

a. CaCO→ CaO + CO2
b. 2FeS2 + \(\frac{11}{2}\)O2 → Fe2O3 + SO2
c. Al2O3.xH2O → Al2O+ xH2O
d. ZnS + \(\frac{3}{2}\)O2 → ZnO + SO2

Choose the correct option:
1. a and b
2. b and c
3. c and d
4. a and c