Among the following reactions, the incomplete combustion of methane is:

1. \(2 {CH}_4+{O}_2 \xrightarrow[]{\mathrm{Cu/523 \ K/100 \ atm}} 2 {CH}_3 {OH}\)
2. \({CH}_4+{O}_2 \xrightarrow[]{{Mo_{2}O_{3}}} {HCHO}+{H}_2 {O}\)
3. \(CH_4 + O_2 → C + 2H_2O\)
4. \(CH_4 + 2O_2 → CO_2 + 2H_2O\)