(i)

The +I effect of the alkyl group increases in the order:

Ethanal < Propanal < Propanone < Butanone The electron density at the carbonyl carbon increases with the increase in the +I effect. As a result, the chances of attack by a nucleophile decrease. Hence, the increasing order of the reactivities of the given carbonyl compounds in nucleophilic addition reactions is:

Butanone < Propanone < Propanal < Ethanal

(ii)

The +I effect is more in ketone than in aldehyde. Hence, acetophenone is the least reactive in nucleophilic addition reactions. Among aldehydes, the +I effect is the highest in p-tolualdehyde because of the presence of the electron-donating −CH₃ group and the lowest in p-nitrobezaldehyde because of the presence of the electron-withdrawing −NO₂ group.

Hence, the increasing order of the reactivities of the given compounds is:

Acetophenone < p-tolualdehyde < Benzaldehyde < p-Nitrobenzaldehyde