In which of the following reactions conc. H2SO4 is used as an oxidising reagent?

a. CaF2 + H2SO4 → CaSO4  + 2 HF
2. 2HI + H2SO4 → I2 + SO2 + 2H2O
3. Cu + 2H2SO4 → CuSO4 + SO2 + 2H2O
4. NaCl + H2SO4  → NaHSO4 + HCl

Choose the correct option:

1. (a, b) 2. (b, c)
3. (c, d) 4. (a, d)