In which of the following pairs, the ions are isoelectronic?

1.  Na+, Mg2+ 

2.  Al3+, O- 

3.  Na+, O2- 

4.  N3-, Cl- 

(a, c)
For, 
Na+=11-1=10e-
Mg2+=12-2=10e-
Thus, they have same number of electrons.
Fo, Al3+=13-3=10e-, O-=8+1=9e-
They do not have same number of electrons.
For, Na+=10e-, O2-=8+2=10e-
They have same number of electrons.
For, N3-=7+3=10e-, Cl-=17+1=18e-
They do not have same number of electrons.
Thus, Na+ is isoelectronic with Mg2+ and O2-.