45.4 L of dinitrogen reacts with 22.7 L of dioxygen to produce 45.4 L of nitrous oxide as per the reaction:
  \(2 \mathrm{~N}_2(\mathrm{~g})+\mathrm{O}_2(\mathrm{~g}) \rightarrow 2 \mathrm{~N}_2 \mathrm{O}(\mathrm{~g})\)
Which of the following statements regarding this reaction are correct?

(a) The reaction follows the Law of Gaseous Volumes.
(b) The volume ratio of reactants (N2: O2) is 2:1.
(c) The reaction violates the Law of Conservation of Mass.
(d) The product N2O has a volume equal to the volume of O2 used.
Options:
1. (a) and (b)
2. (a) and (d)
3. (b) and (c)
4. (c) and (d)
Hint: The law of conservation of mass states that mass is neither created nor destroyed in a chemical reaction.

Explanation:

Step 1: The complete reaction is: 

          \(2N_2(g) \ \ + \ \ O_2(g) \ \ \rightarrow\ \ 2N_2O(g)\)
          45.4 L          22.7L          45.4 L

So, the ratio of the volume of gases is:

 \(V_{N_2} : V_{O_2} : V_{N_2O} \) = \(2:1:2\)

Step 2: The gases are present in a simple whole number ratio. According to Gay Lussac's law, gases combine or are produced in a chemical reaction in a simple ratio by volume, provided that all gases are at the same temperature and pressure.

Hence, the given reaction follows Gay Lussac's law. 

Step 3: This reaction does not violate the law of conservation of mass. As per the stoichiometry, one mole of \(O_2\) reacts with two moles of \(N_2\) to form two moles of \(N_2O\).

Thus, the volume of product formed is not equal to the volume of \(O_2\) consumed. 

Therefore, option 1 is the correct answer.